ChemicalBook >> CAS DataBase List >>Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II)
Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II)
- CAS No.
- 203714-71-0
- Chemical Name:
- Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II)
- Synonyms
- HOVEYDA-GRUBBS CATALYST 1ST;HOVEYDA-GRUBBS CATALYST 1ST GENERATION;Hoveyda-Grubbs G1;Hoveyda-Grubbs 1st;Validamine Impurity 4;Hoveyda-Grubbs Catalyst?M700;Hoveyda-Grubbs Catalyst 2st Generation;DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE) &;Hoveyda-Grubbs Catalyst? M700;Hoveyda-Grubbs Catalyst(TM) 1st Generation
- CBNumber:
- CB3350634
- Molecular Formula:
- C28H45Cl2OPRu
- Molecular Weight:
- 600.61
- MDL Number:
- MFCD03453042
- MOL File:
- 203714-71-0.mol
- MSDS File:
- SDS
Last updated:2026-09-12 18:52:00
| Melting point | 195-197 °C(lit.) |
|---|---|
| storage temp. | 2-8°C |
| solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) |
| form | Solid |
| color | Very Dark Purple |
| InChI | 1S/C18H33P.C10H12O.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-8(2)11-10-7-5-4-6-9(10)3;;;/h16-18H,1-15H2;3-8H,1-2H3;2*1H;/q;;;;+2/p-2 |
| InChIKey | KMKCJXPECJFQPQ-UHFFFAOYSA-L |
| SMILES | P(C1CCCCC1)(C1CCCCC1)C1CCCCC1.C1(C=[Ru](Cl)Cl)=CC=CC=C1OC(C)C |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS02 |
|---|---|
| Signal word | Warning |
| Hazard statements | H228 |
| Precautionary statements | P210 |
| PPE | Eyeshields, Gloves, type N95 (US) |
| Hazard Codes | F |
| Risk Statements | 11 |
| RIDADR | UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all |
| WGK Germany | 3 |
| Storage Class | 4.1B - Flammable solid hazardous materials |
| Hazard Classifications | Flam. Sol. 2 |
Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II) price More Price(18)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 577944 | Hoveyda-Grubbs Catalyst 1st Generation | 203714-71-0 | 100mg | $34.2 | 2026-04-30 | Buy |
| Sigma-Aldrich | 577944 | Hoveyda-Grubbs Catalyst 1st Generation | 203714-71-0 | 2g | $284 | 2026-04-30 | Buy |
| Sigma-Aldrich | 577944 | Hoveyda-GrubbsCatalyst®M700 Umicore | 203714-71-0 | 5G | $629 | 2026-04-30 | Buy |
| TRC | TRC-H700520-500MG | Hoveyda-Grubbs Catalyst 1st Generation | 203714-71-0 | 500mg | $150 | 2026-06-03 | Buy |
| TRC | TRC-H700520-1G | Hoveyda-Grubbs Catalyst 1st Generation | 203714-71-0 | 1g | $247 | 2026-06-03 | Buy |
Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II) Chemical Properties, Uses, Production
Uses
Proven to be useful in Ring-Closing Metathesis (RCM) to form macrocycles. Also employed in a pivotal, macrocyclic ring-closing metathesis in the multi-step synthesis of an HCV protease inhibitor.
reaction suitability
core: ruthenium
reagent type: catalyst
reaction type: Ring Opening Metathesis Polymerisation
Synthesis of Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II) from Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium and Benzene, 1-ethenyl-2-(1-Methylethoxy)-
Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II) Preparation Products And Raw materials
Raw materials
Preparation Products
Global Suppliers ( 132)
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai CoachChem Co., Ltd. | +86-21-67299971；+86-21-67290723 18117322963 | marketing@coachchem.com | China | 96 | 62 |
| xinxiang runyu material co.,Ltd | 03737759608 15690792173 | sales@runvmat.com | China | 300 | 58 |
| PharmaBlock Sciences (Nanjing),Inc. | 025-86918202 4000255188 | sales@pharmablock.com | China | 5000 | 55 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Beijing HwrkChemical Technology Co., Ltd | 89508211 18501085097 | sales.bj@hwrkchemical.com | China | 9407 | 55 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Beijing VSciChem Technology Co., Ltd. | 13811761079 | vscichem@163.com | China | 271 | 64 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| China Langchem Inc. | 0086-21-58956006 | China | 7798 | 57 | |
| Nanjin Cynthia chemicals Technology Co.,Ltd | 0550-5618439 15951861180 | cynthiachem@163.com | China | 291 | 62 |
View Latest Price from Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II) manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-12-23 | Dichloro(o-isopropoxyphenylMethylene)(tricyclohexylphosphine)rutheniuM(II)
203714-71-0
|
1G | 98% | 2KG | XINXIANG RUNYU MATERIAL CO., LTD. | ||
 |
2019-07-31 | DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II)
203714-71-0
|
$1.00 | 1KG | 98% | 10KG | Career Henan Chemical Co |
-
- Dichloro(o-isopropoxyphenylMethylene)(tricyclohexylphosphine)rutheniuM(II)
203714-71-0
- 98%
- XINXIANG RUNYU MATERIAL CO., LTD.
-
- DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II)
203714-71-0
- $1.00
- 98%
- Career Henan Chemical Co
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Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II)
203714-71-0
C28H45Cl2OPRu
Catalysis and Inorganic Chemistry
Metathesis Catalysts
Ru
