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Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine

Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine Structure
Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine structure
CAS No.
142421-57-6
Chemical Name:
Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine
Synonyms
Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine;Bis(3,5-Bis(Trifluoromethyl)Ohenyl)Chlorophosphane;Bis(3,5-bis(trifluoromethyl)phenyl)chlorophosphine;BIS[BIS(3,5-TRIFLUOROMETHYL)PHENYL]CHLOROPHOSPHINE;Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine;bis[3,5-bis(trifluoromethyl)phenyl]-chlorophosphane;Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%;Bis(3,5-di(trifluoroMethyl)phenyl)chlorophosphine,Min.98%;P,P-Bis[3,5-bis(trifluoromethyl)phenyl]phosphinous chloride;Phosphinous chloride, P,P-bis[3,5-bis(trifluoromethyl)phenyl]-
CBNumber:
CB9217634
Molecular Formula:
C16H6ClF12P
Molecular Weight:
492.63
MDL Number:
MFCD01630852
MOL File:
142421-57-6.mol
MSDS File:
SDS
Last updated:2026-09-12 18:56:17
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Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine Properties

Melting point 25-29 °C
Boiling point 333.2±42.0 °C(Predicted)
form liquid
color colorless
Water Solubility Reacts with water.
Sensitive Moisture Sensitive
InChI 1S/C16H6ClF12P/c17-30(11-3-7(13(18,19)20)1-8(4-11)14(21,22)23)12-5-9(15(24,25)26)2-10(6-12)16(27,28)29/h1-6H
InChIKey DFZQEHBNAJGDCT-UHFFFAOYSA-N
SMILES FC(F)(F)c1cc(cc(c1)C(F)(F)F)P(Cl)c2cc(cc(c2)C(F)(F)F)C(F)(F)F
UNSPSC Code 12352002
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)
GHS02,GHS05
Signal word  Danger
Hazard statements  H261-H314
Precautionary statements  P231+P232-P280-P305+P351+P338-P310-P422
PPE Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes  C
Risk Statements  14-34
Safety Statements  26-36/37/39-45
RIDADR  UN3265
WGK Germany  3
HazardClass  8
PackingGroup  II
Storage Class 4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard Classifications Skin Corr. 1B
Water-react 3
NFPA 704
1
3 0

Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 694746 Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine 142421-57-6 500mg $87.7 2026-04-30 Buy
Sigma-Aldrich 694746 Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine 142421-57-6 100mg $49.9 2023-01-07 Buy
Strem Chemicals 15-0114 Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine, min. 98% min.98% 142421-57-6 500mg $54 2026-04-30 Buy
Strem Chemicals 15-0114 Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine, min. 98% min.98% 142421-57-6 2g $159 2026-04-30 Buy
aablocks AA003O6A Phosphinous chloride, P,P-bis[3,5-bis(trifluoromethyl)phenyl]- 95% 142421-57-6 250mg $177 2026-05-28 Buy
Product number Packaging Price Buy
694746 500mg $87.7 Buy
694746 100mg $49.9 Buy
15-0114 500mg $54 Buy
15-0114 2g $159 Buy
AA003O6A 250mg $177 Buy

Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine Chemical Properties, Uses, Production

Uses

Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine synthesis

112981-69-8
142421-57-6
Synthesis of Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine from (3 5 Bis(trifluoromethyl)phenyl)magnesi&

Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine Preparation Products And Raw materials

Raw materials

Phosphinous amide, P,P-bis[3,5-bis(trifluoromethyl)phenyl]-N,N-diethyl- Bis(3,5-bis(trifluoromethyl)phenyl)phosphine oxide (3 5 Bis(trifluoromethyl)phenyl)magnesi& Diethylphosphoramidous dichloride 3,5-Bis(trifluoromethyl)bromobenzene

Preparation Products

Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine Suppliers

Global Suppliers ( 52)
Supplier Tel Email Country ProdList Advantage
Soochow Chirally Material Science and Technology Co.,Ltd 0512-66834346 17751187418 sales@krl-tech.com China 1283 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097 sales.bj@hwrkchemical.com China 9407 55
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Shanghai Macklin Biochemical Co.,Ltd. 15221275939 15221275939 shenlinxing@macklin.cn China 15775 55
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Panjin Infinity Scientific CO. LTD 400-1062016 18612996721 hao@infsci.com China 327 58
Aikon International Limited 025-58859352 15955137747 sales01@aikonchem.com China 16021 58
Supplier Advantage
Soochow Chirally Material Science and Technology Co.,Ltd 58
J & K SCIENTIFIC LTD. 76
Alfa Aesar 84
Beijing HwrkChemical Technology Co., Ltd 55
Energy Chemical 61
Shanghai Hanhong Scientific Co.,Ltd. 64
Shanghai Macklin Biochemical Co.,Ltd. 55
Sigma-Aldrich 80
Panjin Infinity Scientific CO. LTD 58
Aikon International Limited 58

View Latest Price from Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine pictures 2026-08-07 Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine
142421-57-6
 $1.00 1KG 99% 20 tons Shaanxi Dideu Medichem Co. Ltd

142421-57-6 (Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine) Related Search:

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BIS[BIS(3,5-TRIFLUOROMETHYL)PHENYL]CHLOROPHOSPHINE Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+% Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals P,P-Bis[3,5-bis(trifluoromethyl)phenyl]phosphinous chloride bis[3,5-bis(trifluoromethyl)phenyl]-chlorophosphane Bis(3,5-di(trifluoroMethyl)phenyl)chlorophosphine,Min.98% Phosphinous chloride, P,P-bis[3,5-bis(trifluoromethyl)phenyl]- High purity CAS 142421-57-6 BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE in stock Bis(3,5-bis(trifluoromethyl)phenyl)chlorophosphine Bis(3,5-Bis(Trifluoromethyl)Ohenyl)Chlorophosphane Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine 142421-57-6 C16H6ClF12P Catalysis and Inorganic Chemistry Phosphorus Compounds Phosphorus Precursors organophosphine ligand Achiral Phosphine Aryl Phosphine P-Cl