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6-Amino-2-methylbenzoxazole

CAS No.
5676-60-8
Chemical Name:
6-Amino-2-methylbenzoxazole
Synonyms
2-Methyl-6-benzoxazolamine;2-METHYL-6-AMINOBENZOXAZOLE;6-AMINO-2-METHYLBENZOXAZOLE;6-BENZOXAZOLAMINE, 2-METHYL-;2-METHYL-BENZOOXAZOL-6-YLAMINE;2-methylbenzo[d]oxazol-6-amine;2-METHYL-1,3-BENZOXAZOL-6-AMINE;2-METHYL-1,3-BENZOXAZOL-6-AMIN (MFCD0379181)
CBNumber:
CB9294783
Molecular Formula:
C8H8N2O
Molecular Weight:
148.16
MDL Number:
MFCD03791181
MOL File:
5676-60-8.mol
MSDS File:
SDS
Last updated:2026-05-28 06:26:04
Product description Number Pack Size Price
2-Methyl-1,3-benzoxazol-6-amine ≥95% OR110719 1g $52
2-Methyl-1,3-benzoxazol-6-amine ≥95% OR110719 5g $209
2-Methylbenzo[d]oxazol-6-amine 300418 1.00g $62
2-Methylbenzo[d]oxazol-6-amine 300418 5.00g $217
2-Methylbenzo[d]oxazol-6-amine 300418 10.00g $271
More product size

6-Amino-2-methylbenzoxazole Properties

Melting point 144-146°C
Boiling point 290.6±13.0 °C(Predicted)
Density 1.254±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
pka 2.71±0.10(Predicted)
Appearance Brown to black Solid
InChI InChI=1S/C8H8N2O/c1-5-10-7-3-2-6(9)4-8(7)11-5/h2-4H,9H2,1H3
InChIKey NNHTUFOCRUBQCF-UHFFFAOYSA-N
SMILES O1C2=CC(N)=CC=C2N=C1C
CAS DataBase Reference 5676-60-8(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H317-H319
Precautionary statements  P280-P305+P351+P338
Risk Statements  36/37/38-36
Safety Statements  26-36/37/39
RIDADR  2811
HazardClass  IRRITANT
PackingGroup 
HS Code  2934999090

6-Amino-2-methylbenzoxazole price More Price(47)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Apolloscientific OR110719 2-Methyl-1,3-benzoxazol-6-amine ≥95% 5676-60-8 1g $52 2026-06-04 Buy
Apolloscientific OR110719 2-Methyl-1,3-benzoxazol-6-amine ≥95% 5676-60-8 5g $209 2026-06-04 Buy
Matrix Scientific 300418 2-Methylbenzo[d]oxazol-6-amine 5676-60-8 1.00g $62 2026-05-19 Buy
Matrix Scientific 300418 2-Methylbenzo[d]oxazol-6-amine 5676-60-8 5.00g $217 2026-05-19 Buy
Matrix Scientific 300418 2-Methylbenzo[d]oxazol-6-amine 5676-60-8 10.00g $271 2026-05-19 Buy
Product number Packaging Price Buy
OR110719 1g $52 Buy
OR110719 5g $209 Buy
300418 1.00g $62 Buy
300418 5.00g $217 Buy
300418 10.00g $271 Buy

6-Amino-2-methylbenzoxazole Chemical Properties,Uses,Production

Chemical Properties

Light brown powder

Synthesis

2-Methyl-6-nitrobenzoxazole

5683-43-2

6-Amino-2-methylbenzoxazole

5676-60-8

General procedure for the synthesis of 2-methyl-6-amino benzoxazole from 2-methyl-6-nitrobenzoxazole: To a methanolic (60 mL) suspension of 6-nitro-2-methylbenzoxazole (4.00 g, 22.4 mmol) heated to 70 °C, a water (40 mL) solution of ammonium chloride (12.1 g, 0.227 mol) and iron powder (4.52 g, 80.1 mmol). The reaction mixture was stirred at 70 °C for 2 h. After completion of the reaction, it was filtered through diatomaceous earth and washed with methanol. The filtrate was concentrated and the residue was partitioned between water and ethyl acetate. The organic layers were combined and the solvent was removed under reduced pressure to afford the target product 2-methyl-6-aminobenzoxazole in a yield of 2.83 g (85% yield). The product was analyzed by high performance liquid chromatography (HPLC) with 100% purity (System A); low resolution electrospray ionization mass spectrometry (LRESIMS, ESI+) showed m/z = 149 ([M + H]+).

References

[1] Patent: WO2009/150144, 2009, A1. Location in patent: Page/Page column 137
[2] Organic and Biomolecular Chemistry, 2014, vol. 12, # 28, p. 5082 - 5088
[3] Journal of the Chemical Society, 1928, p. 121
[4] Journal of the Chemical Society, 1930, p. 2685,2687
[5] DRP/DRBP Org.Chem.,

6-Amino-2-methylbenzoxazole Preparation Products And Raw materials

Raw materials

1of2

Preparation Products

Global( 101)Suppliers
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View Lastest Price from 6-Amino-2-methylbenzoxazole manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
6-Amino-2-methylbenzoxazole pictures 2026-08-29 6-Amino-2-methylbenzoxazole
5676-60-8
1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
2-Methylbenzo[d]oxazol-6-amine pictures 2022-01-15 2-Methylbenzo[d]oxazol-6-amine
5676-60-8
1KG 99.2% 100 tons Honest Joy Holdings Limited
6-Amino-2-methylbenzoxazole pictures 2020-01-10 6-Amino-2-methylbenzoxazole
5676-60-8
1KG 98%; 99% 500g;1kg; 25kg Career Henan Chemical Co

6-Amino-2-methylbenzoxazole Spectrum

6-BENZOXAZOLAMINE, 2-METHYL- 6-AMINO-2-METHYLBENZOXAZOLE 2-METHYL-6-AMINOBENZOXAZOLE 2-METHYL-1,3-BENZOXAZOL-6-AMINE 2-methylbenzo[d]oxazol-6-amine 2-METHYL-1,3-BENZOXAZOL-6-AMIN (MFCD0379181) 2-METHYL-BENZOOXAZOL-6-YLAMINE 2-Methyl-6-benzoxazolamine 5676-60-8