3-(3-Methoxyphenyl)-1-propene
- CAS No.
- 24743-14-4
- Chemical Name:
- 3-(3-Methoxyphenyl)-1-propene
- Synonyms
- 3-(3-Methoxyphenyl)-1-propene;1-methoxy-3-prop-2-enylbenzene;1-Methoxy-3-(2-propen-1-yl)benzene;Benzene, 1-methoxy-3-(2-propen-1-yl)-;3-(3-Methoxyphenyl)-1-propene,98% (stabilized with MEHQ)
- CBNumber:
- CB9682762
- Molecular Formula:
- C10H12O
- Molecular Weight:
- 148.2
- MDL Number:
- MFCD06201195
- MOL File:
- 24743-14-4.mol
- MSDS File:
- SDS
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H227-H315-H319-H335 |
| Precautionary statements | P305+P351+P338 |
| HS Code | 2909309090 |
3-(3-Methoxyphenyl)-1-propene price More Price(48)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Apolloscientific | OR19549 | 3-Allylanisole 95% | 24743-14-4 | 250mg | $21 | 2026-06-04 | Buy |
| Activate Scientific | AS90575 | 3-Allylanisole 95% | 24743-14-4 | 1g | $116 | 2026-06-04 | Buy |
| Apolloscientific | OR19549 | 3-Allylanisole 95% | 24743-14-4 | 1g | $58 | 2026-06-04 | Buy |
| Activate Scientific | AS90575 | 3-Allylanisole 95% | 24743-14-4 | 5g | $215 | 2026-06-04 | Buy |
| Apolloscientific | OR19549 | 3-Allylanisole 95% | 24743-14-4 | 5g | $209 | 2026-06-04 | Buy |
3-(3-Methoxyphenyl)-1-propene Chemical Properties, Uses, Production
Synthesis
2398-37-0
106-95-6
24743-14-4
The general procedure for the synthesis of 3-(3-methoxyphenyl)-1-propene from m-bromoanisole and 3-bromo-1-propene was as follows: 1. Preparation of the intermediate 1-methyl-3-methoxybenzene (IIa): 3-bromoanisole (40 g, 0.2138 mol) was dissolved in anhydrous THF (220 mL) and added slowly and dropwise to a solution that had been pre-activated (by addition of a small amount of iodine and briefly heated to initiate the reaction) with magnesium (7.9 g, 0.328 mol) in anhydrous THF (20 mL). After 1 hr of reaction, when the solution was gray and most of the magnesium was dissolved, allyl bromide (28.4 mL, 0.328 mol) was added. The reaction was continued for 3 hours and then quenched with saturated NH4Cl solution. The organic layer was extracted with ether and dried over anhydrous Na2SO4, followed by evaporation of the solvent. The crude product was purified by column chromatography on silica gel (230-400 mesh) using a petroleum ether solution of 3-4% ethyl acetate as eluent to afford the allyl compound as a yellow viscous liquid (24 g, 76% yield).
References
[1] Journal of Organic Chemistry, 2013, vol. 78, # 19, p. 9772 - 9780
[2] Journal of Medicinal Chemistry, 1991, vol. 34, # 8, p. 2638 - 2643
[3] Patent: WO2008/135488, 2008, A1. Location in patent: Page/Page column 43
[4] Tetrahedron, 2010, vol. 66, # 34, p. 6965 - 6976
[5] Chemical and Pharmaceutical Bulletin, 2018, vol. 66, # 7, p. 741 - 747
3-(3-Methoxyphenyl)-1-propene Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Shanghai Sinch Parmaceuticals Tech. Co. Ltd. | +86-21-54098501 | sales@sinch.com.cn | China | 11592 | 64 |
| Accela ChemBio Co.,Ltd. | 021-50795510 4000665055 | marketing@accelachem.com | China | 10972 | 64 |
| Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. | 025-66028182 17714375163 | yftan@aikonchem.com | China | 16674 | 50 |
| Shanghai YuanYe Biotechnology Co., Ltd. | 15026964105 | 2881489226@qq.com | China | 89667 | 60 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131885 | 58 |
| 9ding chemical ( Shanghai) Limited | 021-021-52271985 17721149837 | sales@9dingchem.com | China | 19780 | 60 |
| Jiaxing Deyi Chemical Co., Ltd. | 86-0573-85866609 18367600069 | 945717149@qq.com | China | 9506 | 58 |
| Tianjin heowns Biochemical Technology Co., Ltd. | 400-6387771-6039 18920764717 | sales@heowns.com | China | 24636 | 60 |
