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2-FLUORO-6-IODOBENZOIC ACID

2-FLUORO-6-IODOBENZOIC ACID structure

CAS No.: 111771-08-5

Chemical Name:: 2-FLUORO-6-IODOBENZOIC ACID

Synonyms: CAS:111771-08-5;TIMTEC-BB SBB006699;RARECHEM AL BO 0280;2-Fluoro-6-iodobenzoic;2-FLUORO-6-IODOBENZOATE;2-FLUORO-6-IODOBENZOIC ACID;2-Fluoro-6-iodobenzoicAcid>2-Fluoro-6-iodobenzoicacid98%;Benzoic acid, 2-fluoro-6-iodo-;2-Fluoro-6-iodobenzoic acid 98%

CBNumber:: CB9716814

Molecular Formula:: C7H4FIO2

Molecular Weight:: 266.01

MDL Number:: MFCD00042289

MOL File:: 111771-08-5.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-06-25 18:04:04

Product description	Number	Pack Size	Price
2-Fluoro-6-iodobenzoic acid 97%	429910	5g	$228
2-Fluoro-6-iodobenzoic Acid >98.0%(GC)(T)	F0796	1g	$25
2-Fluoro-6-iodobenzoic Acid >98.0%(GC)(T)	F0796	5g	$69
2-Fluoro-6-iodobenzoic acid 98%	PC3782	1g	$54
2-Fluoro-6-iodobenzoic acid 98%	PC3782	5g	$77
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2-FLUORO-6-IODOBENZOIC ACID Properties

Melting point	123-126 °C (lit.)
Boiling point	301.6±27.0 °C(Predicted)
Density	1.9575 (estimate)
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
solubility	soluble in Methanol
pka	1.93±0.10(Predicted)
form	Powder
color	Yellow to light brown
Sensitive	Light Sensitive
BRN	4982371
InChI	1S/C7H4FIO2/c8-4-2-1-3-5(9)6(4)7(10)11/h1-3H,(H,10,11)
InChIKey	CYCXAPWOBWWNRK-UHFFFAOYSA-N
SMILES	OC(=O)c1c(F)cccc1I
CAS DataBase Reference	111771-08-5(CAS DataBase Reference)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

target organs

Respiratory system

PPE

dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-36

WGK Germany

HazardClass

IRRITANT

HS Code

29163990

Storage Class

11 - Combustible Solids

Hazard Classifications

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

NFPA 704

	0
2		0

2-FLUORO-6-IODOBENZOIC ACID price More Price(50)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	429910	2-Fluoro-6-iodobenzoic acid 97%	111771-08-5	5g	$228	2026-04-30	Buy
TCI Chemical	F0796	2-Fluoro-6-iodobenzoic Acid >98.0%(GC)(T)	111771-08-5	1g	$25	2026-04-30	Buy
TCI Chemical	F0796	2-Fluoro-6-iodobenzoic Acid >98.0%(GC)(T)	111771-08-5	5g	$69	2026-04-30	Buy
Apolloscientific	PC3782	2-Fluoro-6-iodobenzoic acid 98%	111771-08-5	1g	$54	2026-06-04	Buy
Apolloscientific	PC3782	2-Fluoro-6-iodobenzoic acid 98%	111771-08-5	5g	$77	2026-06-04	Buy

Product number	Packaging	Price	Buy
429910	5g	$228	Buy
F0796	1g	$25	Buy
F0796	5g	$69	Buy
PC3782	1g	$54	Buy
PC3782	5g	$77	Buy

2-FLUORO-6-IODOBENZOIC ACID Chemical Properties,Uses,Production

Chemical Properties

yellow to light brown powder

Uses

2-Fluoro-6-iodobenzoic acid may be used for the synthesis of fluoro-substituted benzoyl chlorides. It may be used for the one-pot regioselective synthesis of isocoumarins.

General Description

2-Fluoro-6-iodobenzoic acid is loose white crystal. It can be synthesized by using 2-amino-6-fluorobenzoic acid as the starting material.

Synthesis

124-38-9

1121-86-4

111771-08-5

At -70°C, n-butyllithium (n-BuLi, 120 mL) was slowly added dropwise to an ether (300 mL) solution of diisopropylamine (33.33 g, 330.00 mmol). The resulting solution was stirred continuously at -70 °C for 1 h. Subsequently, a solution of 1-fluoro-3-iodobenzene (22.2 g, 100.00 mmol) in ether (100 mL) was added. After continued stirring at -70 °C for 1 h, carbon dioxide (CO2, gas) was passed into the reaction mixture. The reaction mixture was stirred at -50°C for 1 hour. After the reaction was completed, the reaction mixture was extracted with deionized water (1 x 300 mL). The pH of the aqueous layer was adjusted to 1 by dropwise addition of 4 M hydrochloric acid (HCl), followed by extraction of the aqueous layer with ethyl acetate (EtOAc, 3 × 300 mL). The organic layers were combined, washed with saturated saline (2 × 100 mL), dried over anhydrous sodium sulfate (Na2SO4), and concentrated to dryness under reduced pressure to afford 8 g (33% yield) of 2-fluoro-6-iodobenzoic acid as a yellow solid.

References

[1] European Journal of Organic Chemistry, 2002, # 19, p. 3351 - 3358
[2] Synthesis, 2005, # 4, p. 617 - 621
[3] Patent: WO2008/103615, 2008, A1. Location in patent: Page/Page column 41

2-FLUORO-6-IODOBENZOIC ACID Preparation Products And Raw materials

Raw materials

Carbon dioxide 1-Fluoro-3-iodobenzene Diethyl ether Hydrochloric acid n-Butyllithium

N,N-Diisopropylethylamine

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Preparation Products

JNJ-42847922 2-Fluoro-6-(2H-1,2,3-triazol-2-yl)benzoic acid 2-Bromo-6-fluorobenzoic acid

2-FLUORO-6-IODOBENZOIC ACID Suppliers

Global( 202)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29626	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32997	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29766	58
Nanjing Dolon Biotechnology Co.,Ltd.	18905173768	52513593@qq.com	CHINA	2971	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63645	58
Wuhan Chemwish Technology Co., Ltd	027-67849912	sales@chemwish.com	CHINA	10817	58
CONIER CHEM AND PHARMA LIMITED		sales@conier.com	China	49906	58
Fuxin Pharmaceutical	+86-021-021-50872116	contact@fuxinpharm.com	China	9976	58
Antai Fine Chemical Technology Co.,Limited	18503026267	info@antaichem.com	CHINA	9631	58
Shanghai Safer Pharmaceutical Technology Co., Ltd.	021-31761238	sales@saferph.com	CHINA	896	58

Supplier	Advantage
Capot Chemical Co.,Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Nanjing Dolon Biotechnology Co.,Ltd.	58
Alchem Pharmtech,Inc.	58
Wuhan Chemwish Technology Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
Fuxin Pharmaceutical	58
Antai Fine Chemical Technology Co.,Limited	58
Shanghai Safer Pharmaceutical Technology Co., Ltd.	58

View Lastest Price from 2-FLUORO-6-IODOBENZOIC ACID manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2026-06-30	2-FLUORO-6-IODOBENZOIC ACID 111771-08-5		1kg	98%	1000kg	Shaanxi Dideu New Materials Co. Ltd
	2019-07-14	2-FLUORO-6-IODOBENZOIC ACID 111771-08-5	$8.80	1KG	97%-99%	100kg	Career Henan Chemical Co

2-FLUORO-6-IODOBENZOIC ACID
111771-08-5
98%
Shaanxi Dideu New Materials Co. Ltd

2-FLUORO-6-IODOBENZOIC ACID
111771-08-5
$8.80
97%-99%
Career Henan Chemical Co

2-FLUORO-6-IODOBENZOIC ACID Spectrum

2-FLUORO-6-IODOBENZOIC ACID(111771-08-5)¹HNMR 2-FLUORO-6-IODOBENZOIC ACID(111771-08-5)FT-IR 2-FLUORO-6-IODOBENZOIC ACID(111771-08-5)IR

111771-08-5(2-FLUORO-6-IODOBENZOIC ACID)Related Search:

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RARECHEM AL BO 0280 TIMTEC-BB SBB006699 2-FLUORO-6-IODOBENZOIC ACID 2-Fluoro-6-iodobenzoic 2-Fluoro-6-iodobenzoic acid 98% 2-Fluoro-6-iodobenzoicacid98% 2-Fluoro-6-iodobenzoic acid, 98% 1GR 2-Fluoro-6-iodobenzoicAcid> Benzoic acid, 2-fluoro-6-iodo- 2-FLUORO-6-IODOBENZOATE CAS:111771-08-5 111771-08-5 C7H4FIO2 FC6H3ICO2H C7H3FIO2 CARBOXYLIC ACID Building Blocks Organic Building Blocks Carboxylic Acids Carbonyl Compounds C7 Fluorine series C7 Carbonyl Compounds Carboxylic Acids