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2-Fluorobenzoic acid

2-Fluorobenzoic acid Structure
2-Fluorobenzoic acid structure
CAS No.
445-29-4
Chemical Name:
2-Fluorobenzoic acid
Synonyms
OFBA;2-fluorobenzoate;O-FLUOROBENZOIC ACID;2-FLUOROBENZOHYDRAZIDE;ortho-Fluorobenzoic acid;NSC 10319;Adjacent acid;uorobenzoic acid;AKOS BBS-00003806;2-Fluorbenzoesure
CBNumber:
CB3705564
Molecular Formula:
C7H5FO2
Molecular Weight:
140.11
MDL Number:
MFCD00002405
MOL File:
445-29-4.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 04:44:32
Request For Quotation

2-Fluorobenzoic acid Properties

Melting point 122-125 °C (lit.)
Boiling point 114 °C
Density 1,46 g/cm3
storage temp. Sealed in dry,Room Temperature
solubility 7.2g/l
form Crystalline Powder or Needles
pka 3.27(at 25℃)
color White to light yellow
Water Solubility Slightly soluble in water.
BRN 971265
InChI InChI=1S/C7H5FO2/c8-6-4-2-1-3-5(6)7(9)10/h1-4H,(H,9,10)
InChIKey NSTREUWFTAOOKS-UHFFFAOYSA-N
SMILES C(O)(=O)C1=CC=CC=C1F
CAS DataBase Reference 445-29-4(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 64UZ32KOO4
NIST Chemistry Reference Benzoic acid, 2-fluoro-(445-29-4)
EPA Substance Registry System Benzoic acid, 2-fluoro- (445-29-4)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  37/38-36/37/38
Safety Statements  22-26-28-24/25-37/39-36
WGK Germany  3
RTECS  DH0250000
TSCA  TSCA listed
HazardClass  IRRITANT
HS Code  29163900
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
REACH Registrations Inactive
NFPA 704
0
2 0

2-Fluorobenzoic acid price More Price(71)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 412244 2-Fluorobenzoic acid 97% 445-29-4 25g $45.6 2026-04-30 Buy
Sigma-Aldrich 412244 2-Fluorobenzoic acid 97% 445-29-4 100g $91.9 2026-04-30 Buy
TCI Chemical F0035 2-Fluorobenzoic Acid >98.0%(T) 445-29-4 25g $110 2026-04-30 Buy
TCI Chemical F0035 2-Fluorobenzoic Acid >98.0%(T) 445-29-4 500g $1332 2026-04-30 Buy
Strem Chemicals 09-3500 o-Fluorobenzoic acid, min. 97% min.97% 445-29-4 25g $48 2026-04-30 Buy
Product number Packaging Price Buy
412244 25g $45.6 Buy
412244 100g $91.9 Buy
F0035 25g $110 Buy
F0035 500g $1332 Buy
09-3500 25g $48 Buy

2-Fluorobenzoic acid Chemical Properties, Uses, Production

Chemical Properties

white to light yellow crystal powder. soluble in organic solvents such as benzene, toluene, ketone and ether.The corresponding 2-fluorobenzoyl chloride can be obtained by reacting 2-fluorobenzoic acid with an acid chloride agent such as SOCl2, PCl3, etc.

Uses

2-Fluorobenzoic acid is an intermediate of the fungicide tritriazole and meclofenamic acid.

Uses

2-Fluorobenzoic acid may be employed in the preparation of zaragozic acid A analogs. It is also used as an organic chemical synthesis intermediate.

Preparation

The preparation of 2-fluorobenzoic acid is based on anthranilic acid as raw material, adding anhydrous hydrogen fluoride and sodium nitrite in methoxyethyl methyl ether solvent for diazotization, refluxing for 3 hours, and post-processing to obtain the finished product.

Definition

ChEBI: 2-fluorobenzoic acid is a 2-halobenzoic acid that is benzoic acid carrying a fluoro substituent at position 2. It is a fluorobenzoic acid and a 2-halobenzoic acid. It is a conjugate acid of a 2-fluorobenzoate.

Purification Methods

Crystallise the acid from 50% aqueous EtOH, dilute HCl or *C6H6, then purify it by zone melting or vacuum sublimation at 130-140o. [Beilstein 9 H 333. 9 III 1324, 9 IV 950.]

2-Fluorobenzoic acid synthesis

446-52-6
445-29-4
Synthesis of 2-Fluorobenzoic acid from 2-Fluorobenzaldehyde

2-Fluorobenzoic acid Preparation Products And Raw materials

Raw materials

Flutriafol Benzoyl fluoride 2-Fluorobenzoyl chloride Methylic Ether Hydrogen fluoride
Anthranilic acid 2-Fluorophenol

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Preparation Products

1-Boc-4-(2-methoxycarbonylphenyl)piperazine Methyl 2-fluorobenzoate 2-Fluoro-5-nitrobenzoic acid Ataluren alpha-Chloro-o-fluorotoluene
Methyl 2-fluoro-5-nitrobenzoate Methyl 3-fluorobenzoate 2-Morpholinobenzoic acid

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2-Fluorobenzoic acid Suppliers

Global Suppliers ( 568)
Supplier Tel Email Country ProdList Advantage
Shandong Vantage Specialty Chemicals Biotechnology Co., Ltd. 13396369453 18678026865 sdfantai@163.com China 904 58
Weifang Siyuan Chemical Co., Ltd. 0536-8888106 17663601818 2354379876@qq.com China 244 58
Qingdao Yuanhua New Materials Co., Ltd 19015480862; 19015480862 3689187891@qq.com China 254 58
Zibo Run Hang Seng material Technology Co., LTD 13561657928 13561657928 2388773670@qq.com China 294 58
Ningtai Chemical (Shandong) Co., Ltd 15314216173 2045904044@qq.com China 149 58
Qingdao Dexin Chemical Co. LTD 18560810705 354907727@qq.com China 299 58
Shanghai Boyle Chemical Co., Ltd. 021-50182298 021-50180596 sales@boylechem.com China 2202 55
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
INTATRADE GmbH +49 3493/605464 sales@intatrade.de Germany 3563 66
Supplier Advantage
Shandong Vantage Specialty Chemicals Biotechnology Co., Ltd. 58
Weifang Siyuan Chemical Co., Ltd. 58
Qingdao Yuanhua New Materials Co., Ltd 58
Zibo Run Hang Seng material Technology Co., LTD 58
Ningtai Chemical (Shandong) Co., Ltd 58
Qingdao Dexin Chemical Co. LTD 58
Shanghai Boyle Chemical Co., Ltd. 55
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
INTATRADE GmbH 66

Related articles

View Latest Price from 2-Fluorobenzoic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Fluorobenzoic acid pictures 2026-09-15 2-Fluorobenzoic acid
445-29-4
 $58.00-385.00 25g 0.99 25kg Shanghai UCHEM Inc.
2-Fluorobenzoic acid pictures 2026-09-15 2-Fluorobenzoic acid
445-29-4
 1kg 98%min 10000kg WUHAN FORTUNA CHEMICAL CO., LTD
2-Fluorobenzoic acid pictures 2026-09-15 2-Fluorobenzoic acid
445-29-4
 $20.00 1KG 99% 300MT/year Speranza Chemical Co., Ltd.

2-Fluorobenzoic acid Spectrum

2-Fluorobenzoic acid(445-29-4)MS2-Fluorobenzoic acid(445-29-4)1HNMR2-Fluorobenzoic acid(445-29-4)13CNMR2-Fluorobenzoic acid(445-29-4)IR12-Fluorobenzoic acid(445-29-4)IR22-Fluorobenzoic acid(445-29-4)IR3

445-29-4 (2-Fluorobenzoic acid) Related Search:

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NSC 10319 Adjacent acid 2-Fluorobenzoic acid≥ 99% (HPLC) O-FLUOROBENZOIC ACID RARECHEM AL BO 0015 2-FLUOROBENZOIC ACID 2-Fluorobenzoicaid AKOS BBS-00003806 2-fluoro-benzoicaci Benzoic acid, o-fluoro- o-Fluorbenzoesaeure o-fluoro-benzoicaci ortho-Fluorobenzoic acid Fluorobenzoicacidminwhitepowder 2-Fluorobenzoi acid 2-Fluorobenzoicacid,97% o-Fluorobenzoicacid,min.97% Benzoic acid, 2-fluoro- 2-Fluorobenzoicacid98% o-Fluorobenzoic Acid 2-Fluorobenzoic Acid 2-FLUOROICBENZOIC ACID 2-FLUOROBENZOHYDRAZIDE 2 - Fluoro Bezoic Acid o-Fluorobenzoic acid, min. 97% 2-Fluorobenzoic acid,99% 2-Fluorobenzoic acid, 99% 25GR uorobenzoic acid 2-Fluorbenzoesure 2-fluorobenzoate 2-FluorobenzoicAcid> 2-fluoro[carboxyl-14C1]benzoic acid -Fluorobenzoic acid 2-Fluorobenzoic acid, 95% OFBA 445-29-4 Organic Building Blocks Carbonyl Compounds Carboxylic Acids C7 Building Blocks Aryl Fluorinated Building Blocks Building Blocks Carbonyl Compounds organofluorine compounds Aromatics Intermediates & Fine Chemicals Pharmaceuticals C7 Carbonyl Compounds Carboxylic Acids Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts Fluorobenzene FINE Chemical & INTERMEDIATES carboxylic acid| alkyl Fluorine Carboxylic Acids Chemical Synthesis Fluorinated Building Blocks Organic Building Blocks