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Bromocyclohexane

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CAS:108-85-0
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CAS:108-85-0
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CAS:108-85-0
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Bromocyclohexane manufacturers

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  • CAS:108-85-0
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  • CAS:108-85-0
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  • Bromocyclohexane
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  • $50.00 / 1kg
  • 2025-06-20
  • CAS:108-85-0
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  • Purity: 99.9(%)
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Bromocyclohexane Basic information
Product Name:Bromocyclohexane
Synonyms:BROMOCYCLOHEXANE FOR SYNTHESIS;BROMOCYCLOHEXANE;Cyelohexyl bromide;CYCLOHEXYL BROMIDE;1-Bromocyclohexane;bromo-cyclohexan;Bromocylohexane;Cyclohexane,bromo-
CAS:108-85-0
MF:C6H11Br
MW:163.06
EINECS:203-622-2
Product Categories:Alkyl;Building Blocks;Chemical Synthesis;Pharmaceutical Intermediates;Halogen compounds;Halogenated Hydrocarbons;Organic Building Blocks
Mol File:108-85-0.mol
Bromocyclohexane Structure
Bromocyclohexane Chemical Properties
Melting point -57°C
Boiling point 166-167 °C (lit.)
density 1.324 g/mL at 25 °C (lit.)
vapor density 5.62 (vs air)
refractive index n20/D 1.495(lit.)
Fp 145 °F
storage temp. Sealed in dry,Room Temperature
solubility Miscible with ethanol, ether, acetone, benzene and carbon tetrachloride.
form Liquid
color Clear colorless to light yellow
Specific Gravityapproximate 1.33 (20℃)
OdorUnpleasant Odor
Water Solubility insoluble
Sensitive Air & Light Sensitive
Merck 14,2730
BRN 1098373
Dielectric constant7.9(25℃)
Stability:Stable. Combustible. Incompatible with strong oxidizing agents, strong bases.
InChI1S/C6H11Br/c7-6-4-2-1-3-5-6/h6H,1-5H2
InChIKeyAQNQQHJNRPDOQV-UHFFFAOYSA-N
SMILESBrC1CCCCC1
CAS DataBase Reference108-85-0(CAS DataBase Reference)
NIST Chemistry ReferenceCyclohexane, bromo-(108-85-0)
EPA Substance Registry SystemCyclohexane, bromo- (108-85-0)
Safety Information
Hazard Codes Xn
Risk Statements 36/37/38-20-18-52
Safety Statements 23-24/25-37/39-26
WGK Germany 3
RTECS GU7171700
8
TSCA TSCA listed
HS Code 29035990
Storage Class10 - Combustible liquids
Hazard ClassificationsAquatic Chronic 2
MSDS Information
ProviderLanguage
Bromocyclohexane English
SigmaAldrich English
ACROS English
ALFA English
Bromocyclohexane Usage And Synthesis
Chemical Propertiescolourless liquid
UsesBromocyclohexane has been used to study the ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane using vacuum ultraviolet mass-analyzed threshold ionization spectroscopy.
PreparationBromocyclohexane is synthesized by the reaction of cycloethanol and hydrobromic acid.
Synthesis Reference(s)Canadian Journal of Chemistry, 50, p. 3109, 1972 DOI: 10.1139/v72-498
Journal of the American Chemical Society, 112, p. 8212, 1990 DOI: 10.1021/ja00178a080
The Journal of Organic Chemistry, 45, p. 1638, 1980 DOI: 10.1021/jo01297a020
General DescriptionAxial conformer of bromocyclohexane forms inclusion complexes with 9,9′-bianthryl and exhibits a weak 1,3 diaxial Cl...H interaction. It participates in the alkylation reaction of of para-xylene in the presence of graphite as catalyst to yield hydrocarbon.
Purification MethodsShake the bromide with 60% aqueous HBr to remove the free alcohol. After removing excess HBr, the sample is dried and fractionally distilled. [IR: Roberts & Chambers J Am Chem Soc 73 5031 1951, Beilstein 5 III 48, 5 IV 67.]
Tag:Bromocyclohexane(108-85-0) Related Product Information
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