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(R)-1-[(1S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine

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(R)-1-[(1S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine manufacturers

(R)-1-[(1S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine Basic information
Reaction
Product Name:(R)-1-[(1S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine
Synonyms:(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine,min. 97%;(R)1[(1S)2(di-C-hexylphosphino)ferrocen. ]et-dicyclohexylphos;(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine,min.97%;(r,r)-1-dicyclohexylphosphino-2-[1-(dicyclohexylphosphino)ethyl]ferrocene (acc to cas);(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE;(R,R)-1-DICYCLOHEXYLPHOSPHINO-2-[1-(DICYCLOHEXYLPHOSPHINO)ETHYL]FERROCENE;(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine;Josiphos SL-J003-1 /(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine
CAS:167416-28-6
MF:C36H50FeP2
MW:600.59
EINECS:
Product Categories:Chiral Phosphine;Ferrocene Series;Josiphos Series;organophosphine ligand
Mol File:167416-28-6.mol
(R)-1-[(1S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine Structure
(R)-1-[(1S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine Chemical Properties
alpha -139° ±4° (c 0.5, CHCl3)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color orange
InChIKeyLVJMXQBMWBNENE-KHZPMNTOSA-N
SMILES[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(C3CCCCC3)C4CCCCC4)P(C5CCCCC5)C6CCCCC6
CAS DataBase Reference167416-28-6
Safety Information
Risk Statements 36/37/38
Safety Statements 24/25
WGK Germany 3
1-10
HS Code 29310099
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
(R)-1-[(1S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine Usage And Synthesis
Reaction
  1. Ligand for Pd-catalyzed C-N cross-coupling
  2. Ligand for Rh-catalyzed C-N cross-coupling
  3. Ligand for Pd-catalyzed asymmetric synthesis of (S)-QUINAP via dynamic kinetic resolution
  4. Ligand for Ni-catalyzed monoarylation of ammonia
Reactions of 167416-28-6
General Descriptionsold in collaboration with Solvias AG
(R)-1-[(1S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine Preparation Products And Raw materials
Tag:(R)-1-[(1S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine(167416-28-6) Related Product Information
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine (R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldi(3,5-dimethylphenyl)phosphine (R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi(3,5-dimethylphenyl)phosphine (R)-1-[(R)-2-[2-(Diphenylphosphino)phenyl]-ferrocenyl]ethyldicyclohexylphosphine (R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine (R)-(-)-1-[(S)-2-(Di(3,5-dimethyl-4-methoxyphenyl)phosphino)ferrocenyl]ethyldicyclohexylphosphine (R)-1-[(S)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl]-ethyldi-tert-butylphosphine (R)-1-[(1S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (R)-(S)-JOSIPHOS 1,3-Bis(dimethylphosphino)propane 1,3-Bis(dicyclohexylphosphino)propane TRIHEXYLPHOSPHINE Triisopropylphosphine 1,3-Bis(diethylphosphino)propane (S,S)-1-Dicyclohexylphosphino-2-[1-(dicyclohexylphosphino)ethyl]ferrocene (S)-1-[(R)-2-(Dicyclohexylphosphino)-ferrocenyl]ethyldicyclohexylphosphine 1,3-Bis(di-I-propylphosphino)propane (R)-1-[(1S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine