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Alfa Aesar |
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| | METHYL CHLORODIFLUOROACETATE Basic information |
| | METHYL CHLORODIFLUOROACETATE Chemical Properties |
| Boiling point | 79-81 °C(lit.) | | density | 1.37 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.349(lit.) | | Fp | 67 °F | | storage temp. | Keep in dark place,Inert atmosphere,2-8°C | | form | Liquid | | Specific Gravity | 1.371 | | color | Clear colorless | | Sensitive | Moisture Sensitive | | BRN | 1756072 | | InChI | InChI=1S/C3H3ClF2O2/c1-8-2(7)3(4,5)6/h1H3 | | InChIKey | AWUPLMYXZJKHEG-UHFFFAOYSA-N | | SMILES | C(OC)(=O)C(Cl)(F)F | | CAS DataBase Reference | 1514-87-0(CAS DataBase Reference) | | EPA Substance Registry System | Acetic acid, chlorodifluoro-, methyl ester (1514-87-0) |
| Hazard Codes | F,C | | Risk Statements | 11-34-37 | | Safety Statements | 16-26-36/37/39-45 | | RIDADR | UN 2924 3/PG 2 | | WGK Germany | 3 | | F | 19 | | Hazard Note | Highly Flammable/Moisture Sensitive | | TSCA | TSCA listed | | HazardClass | 3 | | PackingGroup | II | | HS Code | 29159000 |
| | METHYL CHLORODIFLUOROACETATE Usage And Synthesis |
| Chemical Properties | CLEAR COLOURLESS LIQUID | | Uses | Methyl chlorodifluoroacetate was used in preparation of 2,2-difluoro-3-hydroxyesters and gem-difluorocyclopropane. | | General Description | Methyl chlorodifluoroacetate is a trifluoromethylating agent. | | Synthesis | Methyl 2-chloro-2,2-difluoroacetate (CH3O(CO)CF2Cl) was synthesized using 1-chloro-1,1,2,2-tetrafluoro-2-methoxyethane (CH3OCF2CF2Cl) as a starting material by performing the reaction according to the reaction conditions of Example 3. Upon completion of the reaction, the target product methyl 2-chloro-2,2-difluoroacetate was obtained in 67% (1.34 mmol) yield. | | References | [1] Patent: US2006/25639, 2006, A1. Location in patent: Page/Page column 4 |
| | METHYL CHLORODIFLUOROACETATE Preparation Products And Raw materials |
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