3-Bromo-4-methoxytoluene

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3-Bromo-4-methoxytoluene manufacturers
3-Bromo-4-methoxytoluene Basic information
Product Name:3-Bromo-4-methoxytoluene
Synonyms:2-bromo-1-methoxy-4-methyl-benzen;Benzene, 2-bromo-1-methoxy-4-methyl-;3-Bromo-4-methoxytoluene 98%;1-Methoxy-2-bromo-4-methylbenzene;2-Bromo-4-methyl-1-methoxybenzene;Methyl(2-bromo-4-methylphenyl) ether;3-Bromo-4-methoxytoluene, 2-Bromo-1-methoxy-4-methylbenzene;1-Bromo-2-methoxy-5-methylbenzene
CAS:22002-45-5
MF:C8H9BrO
MW:201.06
EINECS:244-705-3
Product Categories:Anisoles, Alkyloxy Compounds & Phenylacetates;Bromine Compounds;Aromatic Hydrocarbons (substituted) & Derivatives;Anisole
Mol File:22002-45-5.mol
3-Bromo-4-methoxytoluene Structure
3-Bromo-4-methoxytoluene Chemical Properties
Melting point 15.5 °C(lit.)
Boiling point 124-125 °C20 mm Hg(lit.)
density 1.392 g/mL at 25 °C(lit.)
refractive index n20/D 1.565(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
form liquid
Specific Gravity1.41
color Clear, dark yellow to brown
InChIInChI=1S/C8H9BrO/c1-6-3-4-8(10-2)7(9)5-6/h3-5H,1-2H3
InChIKeyDHPUIKWBNXTXOB-UHFFFAOYSA-N
SMILESC1(OC)=CC=C(C)C=C1Br
CAS DataBase Reference22002-45-5(CAS DataBase Reference)
EPA Substance Registry System2-Bromo-4-methylanisole (22002-45-5)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
TSCA TSCA listed
HazardClass IRRITANT
HS Code 2909309090
Storage Class10 - Combustible liquids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
3-Bromo-4-methoxytoluene Usage And Synthesis
Chemical PropertiesClear colourless to light yellow liquid
Uses2-Bromo-4-methylanisole may be used in the synthesis of:
  • 1,6-bis(2-hydroxy-5-methylphenyl)pyridine (H2mdppy)
  • 1,8-dimethoxy-4-methylanthra-quinone
  • ethyl 2-(2-methoxy-5-methylphenyl)-2-methyl-4-oxocyclopentanecarboxylate
It may be used as starting material in the multi-step synthesis of sesquiterpene (±)-herbertenolide.
Synthesis Reference(s)Synthetic Communications, 23, p. 779, 1993 DOI: 10.1080/00397919308009839
General Description2-Bromo-4-methylanisole can be prepared via bromination of 4-methylanisole using poly(4-vinylpyridinium bromochromate).
3-Bromo-4-methoxytoluene Preparation Products And Raw materials
Preparation Products1-Bromo-2-methoxy-5-methyl-3-nitro-benzene-->3,4-Dimethoxytoluene
Tag:3-Bromo-4-methoxytoluene(22002-45-5) Related Product Information
3-Bromo-4-methoxytoluene 3-Bromo-4-methoxyphenylacetonitrile 3-Bromo-4-methoxyphenylacetic acid 3-Bromo-4-methoxybenzoic acid 4-Bromo-1-methoxy-2-methylbenzene 2-BROMO-5-METHOXYTOLUENE,2-Bromo-5-methoxytoluene 98%,2-Bromo-5-methoxytoluene (4-bromo-3-methylanisole) Tetrabromobisphenol A bis(dibromopropyl ether) 3-Bromo-4-methoxybenzaldehyde 4,4'-Isopropylidenebis[2-(2,6-dibromophenoxy)ethanol] Bromoxynil octanoate Bromoxynil-methyl ether 1-Bromo-3-methoxy-5-methylbenzene EOSIN DIACETATE 3,5-Dibromo-4-methoxybenzoic acid 5-Bromoveratraldehyde Boc-3,5-dibromo-Tyr(OBzl)-OH 5-Bromo-2,4-dimethoxybenzaldehyde 4-Bromo-2-methoxytoluene