|
|
| | (OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) Basic information | | Reaction |
| | (OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) Chemical Properties |
| Melting point | 184-187 °C (lit.) | | Boiling point | 608.2±40.0 °C(Predicted) | | storage temp. | Keep in dark place,Sealed in dry,Room Temperature | | solubility | Chloroform (Slightly), Methanol (Slightly) | | form | Crystalline Powder or Crystals | | color | White to off-white | | BRN | 7729718 | | InChI | InChI=1S/C36H28OP2/c1-5-17-29(18-6-1)38(30-19-7-2-8-20-30)35-27-15-13-25-33(35)37-34-26-14-16-28-36(34)39(31-21-9-3-10-22-31)32-23-11-4-12-24-32/h1-28H | | InChIKey | RYXZOQOZERSHHQ-UHFFFAOYSA-N | | SMILES | C1C=CC(OC2C=CC=CC=2P(C2=CC=CC=C2)C2C=CC=CC=2)=C(P(C2C=CC=CC=2)C2=CC=CC=C2)C=1 | | CAS DataBase Reference | 166330-10-5(CAS DataBase Reference) |
| Hazard Codes | Xn | | Risk Statements | 36/37/38-22 | | Safety Statements | 37/39-26 | | WGK Germany | 3 | | TSCA | No | | HS Code | 29319090 | | Storage Class | 11 - Combustible Solids |
| | (OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) Usage And Synthesis |
| Reaction |
- Useful as a ligand in the Pd-catalyzed formation of diaryl amines.
- Has been recently applied to the C3 benzylation of indoles.
- Has been recently applied to the monoallylation of ammonia.
- Ligand used in the palladium-catalyzed, aerobic oxidation coupling of acyl chlorides with arylboronic acids.
- Ligand used in carbonylation of aryl iodides.
- Ligand used in the direct C-H arylation of benzothiodiazoles.
- Ligand used in stereo-retentive azacyclization of propargylic carbonates.
- Ligand used in palladium catalyzed benzyne trimerization.

| | Chemical Properties | White to off-white crystalline powder or crystals | | Uses | suzuki reaction | | Uses | Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.
Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology | | General Description | This product has been enhanced for catalytic efficiency. | | reaction suitability | reagent type: ligand reaction type: Buchwald-Hartwig Cross Coupling Reaction reagent type: ligand reaction type: Heck Reaction reagent type: ligand reaction type: Hydroaminations reagent type: ligand reaction type: Negishi Coupling reagent type: ligand reaction type: Suzuki-Miyaura Coupling |
| | (OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) Preparation Products And Raw materials |
| Raw materials | Ethanol-->Ethyl acetate-->Tetrahydrofuran-->n-Butyllithium-->Diphenyl ether-->N,N,N',N'-Tetramethylethylenediamine-->Chlorodiphenylphosphine | | Preparation Products | 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline-->Porphine-->4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene |
|