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| | Bis(2-nitrophenyl) disulfide Basic information |
| Product Name: | Bis(2-nitrophenyl) disulfide | | Synonyms: | O-NITROPHENYLDISULFIDE;O,O'-DINITROPHENYL DISULFIDE;Bis-(2-nitrophenyl)-disulfid;Disulfide, bis(2-nitrophenyl);Disulfide, bis(o-nitrophenyl);Disulfide,bis(2-nitrophenyl);o,o'-Dinitrodiphenyl disulfide;1-Nitro-2-[(2-nitrophenyl)disulfanyl]benzene | | CAS: | 1155-00-6 | | MF: | C12H8N2O4S2 | | MW: | 308.33 | | EINECS: | 214-581-5 | | Product Categories: | | | Mol File: | 1155-00-6.mol |  |
| | Bis(2-nitrophenyl) disulfide Chemical Properties |
| Melting point | 194-197 °C (lit.) | | Boiling point | 441.9±30.0 °C(Predicted) | | density | 1.62 g/cm3 (-123.16℃) | | refractive index | 1.6510 (estimate) | | storage temp. | Sealed in dry,Room Temperature | | form | powder to crystal | | color | Light yellow to Brown | | BRN | 1016770 | | InChI | 1S/C12H8N2O4S2/c15-13(16)9-5-1-3-7-11(9)19-20-12-8-4-2-6-10(12)14(17)18/h1-8H | | InChIKey | NXCKJENHTITELM-UHFFFAOYSA-N | | SMILES | [O-][N+](=O)c1ccccc1SSc2ccccc2[N+]([O-])=O | | CAS DataBase Reference | 1155-00-6(CAS DataBase Reference) | | NIST Chemistry Reference | Bis(o-nitrophenyl)disulfide(1155-00-6) | | EPA Substance Registry System | Disulfide, bis(2-nitrophenyl) (1155-00-6) |
| Safety Statements | 22-24/25 | | WGK Germany | 3 | | TSCA | TSCA listed | | HS Code | 29309099 | | Storage Class | 4.1A - Other explosive hazardous materials |
| | Bis(2-nitrophenyl) disulfide Usage And Synthesis |
| Chemical Properties | yellow to yellow-green crystalline powder | | Uses | Bis(o-Nitrophenyl) Disulfide, can be used in a PVC membrane electrode as a sensor for zinc ions. It is also a building block used for the synthesis of various pharmaceutical compounds. It can be used for the preparation of a series of 4-Azaindole inhibitors of c-Met kinase. | | General Description | PVC membrane electrode based on bis(2-nitrophenyl)disulfide carrier acts as sensor for zinc ions. Bis(2-nitrophenyl) disulphide undergoes mechanochemical grinding with bis(4-chlorophenyl)disulfide in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene catalyst via metathesis reaction to yield non-symmetrical heterodimer 4-chlorophenyl-2′-nitrophenyl disulfide. | | Purification Methods | Purify the disulfide by recrystallisation from glacial AcOH or from *C6H6 and the yellow needles are dried in an oven at 100o until the odour of the solvent is absent. It is sparingly soluble in EtOH and Me2CO. [Bogert & Stull Org Synth Coll Vol I 220 1941, Bauer & Cymerman J Chem Soc 3434 1949, Beilstein 6 IV 1672.] |
| | Bis(2-nitrophenyl) disulfide Preparation Products And Raw materials |
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