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| | TRANS-DICHLOROBIS(TRIETHYLPHOSPHINE)PALLADIUM(II) Basic information |
| | TRANS-DICHLOROBIS(TRIETHYLPHOSPHINE)PALLADIUM(II) Chemical Properties |
| Melting point | 139-142 °C(lit.) | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | solubility | Soluble in chloroform, toluene and benzene | | form | Powder | | color | Yellow | | Sensitive | Hygroscopic | | InChI | 1S/2C6H15P.2ClH.Pd/c2*1-4-7(5-2)6-3;;;/h2*4-6H2,1-3H3;2*1H;/q;;;;+2/p-2 | | InChIKey | ULYNIEUXPCUIEL-UHFFFAOYSA-L | | SMILES | Cl[Pd]Cl.CCP(CC)CC.CCP(CC)CC |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | RIDADR | UN3464 | | WGK Germany | 3 | | HazardClass | 6.1 | | PackingGroup | III | | HS Code | 28439090 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | TRANS-DICHLOROBIS(TRIETHYLPHOSPHINE)PALLADIUM(II) Usage And Synthesis |
| Chemical Properties | Yellow powder | | Uses | trans-Dichlorobis(triethylphosphine)palladium(II) is used in coupling of C-C bonds. It is also used as pharmaceutical and organic Intermediates. | | reaction suitability | core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst | | Synthesis | Weigh PdCl2, dissolved in 1:1 hydrochloric acid, weigh triethylphosphine, dissolved in 200 mL of anhydrous ethanol, add PdCl2 solution under stirring, heated to boiling, reflux reaction for 4 h, to get a yellow precipitate, filtered while hot, washed with anhydrous ethanol for 2 times, and then washed with ethyl ether for 2 times, 50% vacuum drying for 2 h, to get the bis(triethylphosphine)palladium(II) chloride, the yield 98.5%. |
| | TRANS-DICHLOROBIS(TRIETHYLPHOSPHINE)PALLADIUM(II) Preparation Products And Raw materials |
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