3-Bromo-4-fluoronitrobenzene

3-Bromo-4-fluoronitrobenzene Suppliers list

Company Name:	Liaoning Tianhua Chemical Co., Ltd.
Tel:	0418-6530555 2855550
Email:

Company Name:	3B Pharmachem (Wuhan) International Co.,Ltd.
Tel:	18930552037
Email:	3bsc@sina.com

Company Name:	TCI (Shanghai) Development Co., Ltd.
Tel:	021-67121386
Email:	Sales-CN@TCIchemicals.com

3-Bromo-4-fluoronitrobenzene manufacturers

3-Bromo-4-fluoronitrobenzene Basic information

Product Name:	3-Bromo-4-fluoronitrobenzene
Synonyms:	2-FLUORO-5-NITROBROMOBENZENE;3-BROMO-4-FLUORONITROBENZENE;3-Bromo-4-fluoro-1-nitrobenzene;3-BROMO-4-FLUORONITROBENZENE, 98+%;1-Fluoro-2-bromo-4-nitrobenzene;Benzene, 2-broMo-1-fluoro-4-nitro-;2-Bromo-1-fluoro-4-nitrobenzene 95%;Benzene, 2-broMo
CAS:	701-45-1
MF:	C6H3BrFNO2
MW:	220
EINECS:	211-855-6
Product Categories:	Fluorinated benzene series;blocks;Bromides;FluoroCompounds;NitroCompounds
Mol File:	701-45-1.mol

3-Bromo-4-fluoronitrobenzene Chemical Properties

Melting point	55°C
Boiling point	250.6±20.0 °C(Predicted)
density	1.808±0.06 g/cm3(Predicted)
Fp	105°
storage temp.	Sealed in dry,Room Temperature
form	Solid
color	White or Colorless to Light yellow to Light orange
Water Solubility	Slightly soluble in water.
InChI	1S/C6H3BrFNO2/c7-5-3-4(9(10)11)1-2-6(5)8/h1-3H
InChIKey	FAWMTDSAMOCUAR-UHFFFAOYSA-N
SMILES	[O-][N+](=O)c1ccc(F)c(Br)c1
CAS DataBase Reference	701-45-1(CAS DataBase Reference)

Safety Information

MSDS Information

3-Bromo-4-fluoronitrobenzene Usage And Synthesis

Chemical Properties	Light yellow solid
Uses	Reatant in the synthesis of N-fused tricyclic indoles, dimethyamine, benzofuran.
Synthesis Reference(s)	The Journal of Organic Chemistry, 63, p. 8448, 1998 DOI: 10.1021/jo981557o
Synthesis	7439-89-6 350-46-9 701-45-1 Example 4: 3.0 g (0.054 mol) of iron powder was added to 250 g (1.77 mol) of 4-fluoronitrobenzene and the mixture was heated to 140 °C. Over a period of 9 hours, 450 g (2.81 mol) of bromine was slowly added dropwise and supplemented with 15 g (0.27 mol) of iron powder in batches. After the dropwise addition was completed, stirring of the reaction mixture was continued for 6 hours. After completion of the reaction, the mixture was filtered and the filtrate was dissolved in 530 g of hot hexane. After cooling the solution, 220 g of 3-bromo-4-fluoronitrobenzene crystals precipitated in a yield of 55.8% of the theoretical value, with the product having a melting point of 55.5°C-56.5°C and a purity of 99.0%.
References	[1] Patent: US4446075, 1984, A

3-Bromo-4-fluoronitrobenzene Preparation Products And Raw materials

Raw materials	4-Fluoronitrobenzene-->Iron-->2-Bromofluorobenzene-->Hexane
Preparation Products	ABBV-075-->1-(2-BroMo-4-nitrophenyl)pyrrolidine-->2-(2-bromo-4-nitrophenyl)acetonitrile

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