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Bis(3,5-dimethylphenyl)phosphine

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Bis(3,5-dimethylphenyl)phosphine manufacturers

Bis(3,5-dimethylphenyl)phosphine Basic information
Product Name:Bis(3,5-dimethylphenyl)phosphine
Synonyms:Bis(3,5-dimethylphenyl)phosphine,99%;98% [(CH3)2C6H3]2PH;Bis(3,5-diMethylphenyl)phosphine, 98% (10% solution in hexanes);Phosphine, bis(3,5-dimethylphenyl)-;Bis(3,5-dimethylphenyl);bis(3,5-dimethylphenyl)phosphane;Bis(3,5-dimethylphenyl)phosphine, 98% (10wt% in hexanes);Bis(3,5-dimethyL
CAS:71360-06-0
MF:C16H19P
MW:242.3
EINECS:
Product Categories:organophosphine
Mol File:71360-06-0.mol
Bis(3,5-dimethylphenyl)phosphine Structure
Bis(3,5-dimethylphenyl)phosphine Chemical Properties
Boiling point 368.8±42.0 °C(Predicted)
density 1.017 g/mL at 25 °C
refractive index n20/D1.599
Fp >110℃
form liquid
color colorless
Sensitive air sensitive
InChIInChI=1S/C16H19P/c1-11-5-12(2)8-15(7-11)17-16-9-13(3)6-14(4)10-16/h5-10,17H,1-4H3
InChIKeyGPFIUEZTNRNFGD-UHFFFAOYSA-N
SMILESP(C1=CC(C)=CC(C)=C1)C1=CC(C)=CC(C)=C1
Safety Information
Hazard Codes Xn
Risk Statements 22
Safety Statements 26-36/37/39
RIDADR UN 3334
WGK Germany 3
HS Code 29319090
Storage Class10 - Combustible liquids
Hazard ClassificationsAcute Tox. 4 Oral
MSDS Information
Bis(3,5-dimethylphenyl)phosphine Usage And Synthesis
Chemical PropertiesColorless liquid
UsesBis(3,5-dimethylphenyl)phosphine can be used as a reactant to prepare:
  • Iron(II) chiral diimine diphosphine complexes as catalysts for the asymmetric transfer hydrogenation of ketones.
  • The complex of iridium with biphenol phosphite-phosphine bidentate ligand as an asymmetric catalyst for the hydrogenation of N-arylimines.
  • Chiral phosphines with excellent stereoselectivity by 1, 4 addition reaction with α,β-unsaturated aldehydes using a palladium catalyst.
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
Bis(3,5-dimethylphenyl)phosphine Preparation Products And Raw materials
Raw materialsPhosphinous acid, P,P-bis(3,5-dimethylphenyl)--->Lithium, (3,5-dimethylphenyl)--->(XYL)2P(O)H-->5-Bromo-m-xylene
Preparation ProductsTriethyl borate
Tag:Bis(3,5-dimethylphenyl)phosphine(71360-06-0) Related Product Information
Bis(3,5-dimethylphenyl)phosphine Bis(3,5-dimethylphenyl)phosphine oxide ,97%,BIS(3,5-DIMETHYLPHENYL)PHOSPHINE OXIDE (R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-dimethylphenyl)phosphine] Bis(3,5-dimethyl-4-methoxyphenyl)chlorophosphine Bis(3,5-dimethylphenyl)chlorophosphine Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine Tris[3,5-bis(trifluoromethyl)phenyl]phosphine (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl 1,2-Bis[bis(3,5-ditrifluoromethylphenyl)phosphino]ethane 1,2-Bis[bis(3,5-dimethylphenyl)phosphino]ethane Bis[bis(3,5-ditrifluoromethylphenyl)phosphino]methane 1,3-Bis[bis(3,5-dimethylphenyl)phosphino]propane Bis(3,5-dimethyl-4-methoxyphenyl)phosphine 1,4-Bis[bis(3,5-dimethylphenyl)phosphino]butane (S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-dimethylphenyl)phosphine] 1,4-Bis[bis(3,5-ditrifluoromethylphenyl)phosphino]butane Methyl-alpha-D-glucopyranoside-2,6-dibenzoate-3,4-di(bis(3,5-dimethylphenyl)phosphinite) 1,5-Bis[bis(3,5-dimethylphenyl)phosphino]pentane