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4-Amino-3-bromopyridine

4-Amino-3-bromopyridine Structure
4-Amino-3-bromopyridine structure
CAS No.
13534-98-0
Chemical Name:
4-Amino-3-bromopyridine
Synonyms
1H-PYRAZOLE-5-CARBOXYLIC ACID;AKOS PAO-0460;AKOS BBS-00005959;IFLAB-BB F3250-0675;3-Bromo-4-pyridinamine;3-Bromo-4-aminopyridine;4-AMINO-3-BROMOPYRIDINE;4-Pyridinamine, 3-bromo-;4--3- aMinopyridinebroMide;4-Amino-3-bromopyridine,98%
CBNumber:
CB0244790
Molecular Formula:
C5H5BrN2
Molecular Weight:
173.01
MDL Number:
MFCD02068297
MOL File:
13534-98-0.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-27 17:23:47
Product description Number Pack Size Price
4-Amino-3-bromopyridine 97% 685224 1g $85.2
4-Amino-3-bromopyridine 97% 685224 5g $405
4-Amino-3-bromopyridine Asreported 261243 2g $333
4-Amino-3-bromopyridine Asreported 261243 5g $488
4-Amino-3-bromopyridine Asreported 261243 10g $659
More product size
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4-Amino-3-bromopyridine Properties

Melting point 61-69 °C
Boiling point 275.8±20.0 °C(Predicted)
Density 1.6065 (rough estimate)
refractive index 1.5182 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka pK1: 7.04(+1) (20°C)
form Crystalline Powder
color White to off-white
BRN 110183
InChI InChI=1S/C5H5BrN2/c6-4-3-8-2-1-5(4)7/h1-3H,(H2,7,8)
InChIKey DDQYSZWFFXOXER-UHFFFAOYSA-N
SMILES C1=NC=CC(N)=C1Br
CAS DataBase Reference 13534-98-0(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Exclamation Mark (GHS07)
GHS05,GHS07
Signal word  Danger
Hazard statements  H302-H315-H318-H335
Precautionary statements  P280-P301+P312+P330-P302+P352-P305+P351+P338+P310
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-41-37/38-22
Safety Statements  26-36/37/39-37/39-39
WGK Germany  3
HazardClass  IRRITANT, AIR SENSITIVE
HS Code  29333990
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Eye Dam. 1
Skin Irrit. 2
STOT SE 3
NFPA 704
1
2 0

4-Amino-3-bromopyridine price More Price(86)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 685224 4-Amino-3-bromopyridine 97% 13534-98-0 1g $85.2 2023-06-20 Buy
Sigma-Aldrich 685224 4-Amino-3-bromopyridine 97% 13534-98-0 5g $405 2023-06-20 Buy
Usbiological 261243 4-Amino-3-bromopyridine Asreported 13534-98-0 2g $333 2026-06-03 Buy
Usbiological 261243 4-Amino-3-bromopyridine Asreported 13534-98-0 5g $488 2026-06-03 Buy
Usbiological 261243 4-Amino-3-bromopyridine Asreported 13534-98-0 10g $659 2026-06-03 Buy
Product number Packaging Price Buy
685224 1g $85.2 Buy
685224 5g $405 Buy
261243 2g $333 Buy
261243 5g $488 Buy
261243 10g $659 Buy

4-Amino-3-bromopyridine Chemical Properties,Uses,Production

Uses

4-Amino-3-bromopyridine is used as an intermediate in organic synthesis and pharmaceuticals.

Chemical Properties

yellow Cryst

Synthesis

4-Aminopyridine

504-24-5

4-Amino-3-bromopyridine

13534-98-0

General procedure for the synthesis of 4-amino-3-bromopyridine from 4-aminopyridine: To a mixture of 4-aminopyridine (20.0 g, 0.21 mol) and acetonitrile (300.0 mL) was added N-bromosuccinimide (NBS) (39.8 g, 0.22 mol) in batches at 0 °C, the reaction was to be carried out protected from light. Subsequently, the reaction mixture was stirred at room temperature for 24 hours. The progress of the reaction was monitored by thin layer chromatography (TLC) and after confirming the completion of the reaction, the mixture was cooled to room temperature and filtered. The filtrate was concentrated under reduced pressure and the residue was purified by fast column chromatography (silica gel as stationary phase and dichloromethane/methanol=20:1 as eluent) to afford the target compound 4-amino-3-bromopyridine (33.2 g, 91.4% yield) as a light yellow solid. Mass spectrum (ESI) m/z: 172.9 [M + H]+.

References

[1] European Journal of Medicinal Chemistry, 2016, vol. 120, p. 37 - 50
[2] Organic and Biomolecular Chemistry, 2017, vol. 15, # 15, p. 3216 - 3231
[3] Patent: US2003/22883, 2003, A1
[4] Journal of the American Chemical Society, 2012, vol. 134, # 31, p. 12928 - 12931

4-Amino-3-bromopyridine Preparation Products And Raw materials

Raw materials

Methyl vinyl sulfone 4-Aminopyridine N-Bromosuccinimide Acetonitrile

Preparation Products

3-Bromo-4-hydroxypyridine 2,2-DIMETHYL-N-PYRIDIN-4-YL-PROPIONAMIDE 1-N-(cyclohexylmethyl)benzene-1,2-diamine 4-(Acetylamino)-3-bromopyridine ETHYL 3-(2-AMINOPYRIDIN-3-YL)ACRYLATE

4-Amino-3-bromopyridine Suppliers

Global( 350)Suppliers
Supplier Tel Email Country ProdList Advantage
Dideu Industries Group Limited 		+86-29-89586680 +86-15129568250 1059@dideu.com China 29093 58
Hebei Chuanghai Biotechnology Co., Ltd 		+8615531151365 mina@chuanghaibio.com China 18126 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 20120 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806 sales@capot.com China 29640 60
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29812 58
Shenzhen Nexconn Pharmatechs Ltd 		+86-755-89396905 +86-15013857715 admin@nexconn.com China 10403 58
Nanjing Dolon Biotechnology Co.,Ltd. 		18905173768 52513593@qq.com CHINA 2972 58
Accela ChemBio Inc. 		+1-858-6993322 info@accelachem.com United States 21193 58
Alchem Pharmtech,Inc. 		8485655694 sales@alchempharmtech.com United States 63687 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49979 58
Supplier Advantage
Dideu Industries Group Limited 		58
Hebei Chuanghai Biotechnology Co., Ltd 		58
Henan Fengda Chemical Co., Ltd 		58
Capot Chemical Co.,Ltd. 		60
career henan chemical co 		58
Shenzhen Nexconn Pharmatechs Ltd 		58
Nanjing Dolon Biotechnology Co.,Ltd. 		58
Accela ChemBio Inc. 		58
Alchem Pharmtech,Inc. 		58
CONIER CHEM AND PHARMA LIMITED 		58

View Lastest Price from 4-Amino-3-bromopyridine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
3-Bromo-4-pyridinamine pictures 2026-07-09 3-Bromo-4-pyridinamine
13534-98-0
 $1.00-200.00 1KG 99%, 99.5% Sublimated Henan Fengda Chemical Co., Ltd
4-Amino-3-bromopyridine pictures 2026-07-06 4-Amino-3-bromopyridine
13534-98-0
 $85.00-850.00 10kg 0.99 20tons Zibo Hangyu Biotechnology Development Co., Ltd
4-Amino-3-bromopyridine pictures 2026-06-30 4-Amino-3-bromopyridine
13534-98-0
 1KG 98.0% 10000KGS Shaanxi Dideu New Materials Co. Ltd

4-Amino-3-bromopyridine Spectrum

4-Amino-3-bromopyridine(13534-98-0)1HNMR

13534-98-0(4-Amino-3-bromopyridine)Related Search:

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IFLAB-BB F3250-0675 AKOS BBS-00005959 AKOS PAO-0460 4-AMINO-3-BROMOPYRIDINE 3-Bromo-4-aminopyridine 3-Bromo-4-pyridinamine 3-Bromo-4-aminopyridine, 3-Bromo-4-pyridinamine 4-Amino-3-bromopyridine ,97% 4-AMino-3-broMopyridine, 98% 1GR 4-Amino-3-bromopyridine,98% 4--3- aMinopyridinebroMide 4-Pyridinamine, 3-bromo- 4-Amino-3-bromopyridine ISO 9001：2015 REACH 4-Amino-3-bromopyridine,98% min 4-Amino-3-bromopyridine / 3-Bromopyridin-4-amine 1H-PYRAZOLE-5-CARBOXYLIC ACID 13534-98-0 Amines Pyridines Pyridine