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Methyl vinyl sulfone

CAS No.
3680-02-2
Chemical Name:
Methyl vinyl sulfone
Synonyms
(Methylsulfonyl)ethene;VINYL METHYL SULFONE;DK762;URI 718;sulfone,methylvinyl;METHYL VINYL SULFONE;Sulfone, methyl vinyl;METHYL VINYL SULPHONE;Methanesulfonylethene;(methylsulfonyl)-ethen
CBNumber:
CB3465691
Molecular Formula:
C3H6O2S
Molecular Weight:
106.14
MDL Number:
MFCD00007567
MOL File:
3680-02-2.mol
MSDS File:
SDS
Last updated:2026-05-28 06:32:33
Product description Number Pack Size Price
Methyl vinyl sulfone ≥97% 247197 5g $105
Methyl vinyl sulfone ≥97% 247197 25g $170
Vinyl methyl sulfone 468691 1g $389
Vinyl methyl sulfone 468691 10g $531
Methyl vinylsulfone FM149139 0.5g $150
More product size

Methyl vinyl sulfone Properties

Boiling point 115-117 °C19 mm Hg(lit.)
Density 1.212 g/mL at 25 °C(lit.)
refractive index n20/D 1.463(lit.)
Flash point >230 °F
storage temp. 2-8°C
form Liquid
Specific Gravity 1.212
color Clear colorless to slightly yellow
BRN 878198
Stability Stable. Incompatible with strong oxidizing agents. Irritant.
InChI InChI=1S/C3H6O2S/c1-3-6(2,4)5/h3H,1H2,2H3
InChIKey WUIJTQZXUURFQU-UHFFFAOYSA-N
SMILES C=CS(C)(=O)=O
CAS DataBase Reference 3680-02-2(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII T6N4PU5BSH
NIST Chemistry Reference Ethene, (methylsulfonyl)-(3680-02-2)
EPA Substance Registry System Ethene, (methylsulfonyl)- (3680-02-2)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Skull and Crossbones (GHS06)
GHS05,GHS06
Signal word  Danger
Hazard statements  H302-H310-H318
Precautionary statements  P262-P264-P280-P301+P312-P302+P352+P310-P305+P351+P338
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  T+,T,Xi
Risk Statements  22-27-41
Safety Statements  26-28-36/37/39-45-28A
RIDADR  UN 2810 6.1/PG 1
WGK Germany  3
RTECS  WR6825000
HazardClass  6.1
PackingGroup  II
HS Code  29309099
Storage Class 6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
Hazard Classifications Acute Tox. 2 Dermal
Acute Tox. 4 Oral
Eye Dam. 1
Excepted Quantities Max Inner Pack (1g or 1ml) and Max Outer Pack (300g or 300ml)
NFPA 704
1
4 0

Methyl vinyl sulfone price More Price(34)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 247197 Methyl vinyl sulfone ≥97% 3680-02-2 5g $105 2023-01-07 Buy
Sigma-Aldrich 247197 Methyl vinyl sulfone ≥97% 3680-02-2 25g $170 2023-01-07 Buy
Usbiological 468691 Vinyl methyl sulfone 3680-02-2 1g $389 2026-06-03 Buy
Usbiological 468691 Vinyl methyl sulfone 3680-02-2 10g $531 2026-06-03 Buy
Biosynth FM149139 Methyl vinylsulfone 3680-02-2 0.5g $150 2026-06-04 Buy
Product number Packaging Price Buy
247197 5g $105 Buy
247197 25g $170 Buy
468691 1g $389 Buy
468691 10g $531 Buy
FM149139 0.5g $150 Buy

Methyl vinyl sulfone Chemical Properties,Uses,Production

Chemical Properties

light yellow liquid

Uses

Methyl vinyl sulfone has been used:

  • as derivatization reagent in an improved method for detection of pseudouridine in nucleoside mixtures by capillary HPLC-mass spectrometry
  • in preparation of methylsulfonylethyl cellulose via Michael addition to cotton fabric
  • in Heck vinylation of aryl halides

General Description

Clear pale yellow liquid.

Air & Water Reactions

Water soluble.

Reactivity Profile

Methyl vinyl sulfone is incompatible with oxidizing agents . Can react exothermically with reducing agents to release hydrogen gas or hydrogen sulfide. In the presence of various catalysts (such as acids) or initiatiators, can undergo exothermic polymerization reactions.

Fire Hazard

Methyl vinyl sulfone is probably combustible.

Purification Methods

Pass the sulfone through a column of alumina, then de-gas, distil it in a vacuum line and store it at -190o until required. [Beilstein 1 III 1866.]

15205-66-0
124-63-0
191604-52-1
3680-02-2
Synthesis of Methyl vinyl sulfone from 2-(METHYLSULFONYL)ETHANOL and Methanesulfonyl chloride
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VINYL METHYL SULFONE (methylsulfonyl)-ethen 1-(Methylsulfonyl)ethylene Sulfone, methyl vinyl sulfone,methylvinyl URI 718 METHYL VINYL SULFONE METHYL VINYL SULPHONE Methyl vinyl sulfone, stabilized, 98% Ethene, (methylsulfonyl)- METHYL VINYL SULFONE , STABILIZED WITH 200PPM 4-T-BUTYLPHENOL METHYL VINYL SULFONE, 98%, STABILIZED Ethenyl methyl sulfone Methyl ethenyl sulfone Methyl vinyl sulfone, 98%, stab. with 200ppm 4-tert-butylphenol (methylsulphonyl)ethylene Methylvinylsulfone,98%,stab.with200ppm4-t-butylphenol Methyl vinyl sulfone 98% Methanesulfonylethene Methyl vinyl sulfone, stabilized with 200ppm 4-tert-butylphenol methyl ethenyl sulphone Methyl vinyl sulfone, 98%, stab with 200ppm 4-tert-butylphen 1-methylsulfonylethene DK762 Methyl vinyl sulfone >=97% (Methylsulfonyl)ethene 3680-02-2 3680-2-2 650-16-6 H2CCHSO2CH3 Building Blocks Sulfones Sulfur Compounds Organic Building Blocks Organic Building Blocks Sulfones Sulfur Compounds