ChemicalBook >> CAS DataBase List >>Methyl 2-Methyl-4-nitrobenzoate

Methyl 2-Methyl-4-nitrobenzoate

Methyl 2-Methyl-4-nitrobenzoate structure

CAS No.: 62621-09-4

Chemical Name:: Methyl 2-Methyl-4-nitrobenzoate

Synonyms: Benzoic acid, 2-Methyl-4-nitro-, Methyl ester;Methyl 4-Nitro-o-toluate;Methyl 4-Nitro-2-Methylbenzoate;Methyl 2-Methyl-4-nitrobenzoate;Methyl2-Methyl-4-nitrobenzoate>4-Nitro-o-toluic Acid Methyl Ester;_x005f\rMethyl 2-Methyl-4-nitrobenzoate;2-Methyl-4-nitrobenzoic acid methyl ester;2-Pyridinecarboxylicacid,7-(trifluoromethyl)-

CBNumber:: CB21513745

Molecular Formula:: C9H9NO4

Molecular Weight:: 195.17

MDL Number:: MFCD03618407

MOL File:: 62621-09-4.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-05-27 23:56:49

Request For Quotation

Methyl 2-Methyl-4-nitrobenzoate Properties

Melting point	74.0 to 78.0 °C
Boiling point	315.4±30.0 °C(Predicted)
Density	1+-.0.06 g/cm3(Predicted)
storage temp.	Sealed in dry,Room Temperature
solubility	soluble in Methanol
form	powder to crystal
color	White to Light yellow
InChI	InChI=1S/C9H9NO4/c1-6-5-7(10(12)13)3-4-8(6)9(11)14-2/h3-5H,1-2H3
InChIKey	JJHCLPDHYBSSHC-UHFFFAOYSA-N
SMILES	C(OC)(=O)C1=CC=C([N+]([O-])=O)C=C1C
FDA UNII	WFH9F997GL

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H315-H319-H335
Precautionary statements	P261-P305+P351+P338
HS Code	2916399090

Methyl 2-Methyl-4-nitrobenzoate price More Price(45)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TCI Chemical	M2545	Methyl 2-Methyl-4-nitrobenzoate >98.0%(GC)	62621-09-4	5g	$74	2026-04-30	Buy
TCI Chemical	M2545	Methyl 2-Methyl-4-nitrobenzoate >98.0%(GC)	62621-09-4	25g	$293	2026-04-30	Buy
Usbiological	284550	2-Methyl-4-nitro-benzoic acid methyl ester Asreported	62621-09-4	2g	$355	2026-06-03	Buy
Usbiological	284550	2-Methyl-4-nitro-benzoic acid methyl ester Asreported	62621-09-4	5g	$582	2026-06-03	Buy
Usbiological	284550	2-Methyl-4-nitro-benzoic acid methyl ester Asreported	62621-09-4	10g	$812	2026-06-03	Buy

Product number	Packaging	Price	Buy
M2545	5g	$74	Buy
M2545	25g	$293	Buy
284550	2g	$355	Buy
284550	5g	$582	Buy
284550	10g	$812	Buy

Methyl 2-Methyl-4-nitrobenzoate Chemical Properties,Uses,Production

Uses

methyl 2-methyl-4-nitrobenzoate is a useful research chemical.

Synthesis

67-56-1

1975-51-5

62621-09-4

General procedure for the synthesis of methyl 2-methyl-4-nitrobenzoate from methanol and 2-methyl-4-nitrobenzoic acid: 1. SOCl was added slowly and dropwise to a methanolic solution of 2-methyl-4-nitrobenzoic acid (3 g, 16.5 mmol). 2. the reaction mixture was stirred continuously at 70 °C for 18 hours. 3. After completion of the reaction, the solvent was removed by evaporation and the residue was diluted with ether. 4. The ether phase was washed sequentially with water and 1N NaOH solution. 5. 5. The organic phase was dried with anhydrous NaSO, filtered and the solvent was evaporated to give methyl 2-methyl-4-nitrobenzoate as a dark yellow solid (3.25 g, quantitative yield). NMR data: 1H NMR (300 MHz, CDCl) δ: 7.95 (m, 3H), 3.86 (s, 3H), 2.59 (s, 3H).

References

[1] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 3, p. 942 - 945
[2] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 3, p. 946 - 949
[3] Patent: WO2009/47240, 2009, A1. Location in patent: Page/Page column 28
[4] Journal of Medicinal Chemistry, 1999, vol. 42, # 18, p. 3510 - 3519
[5] Patent: CN103804358, 2016, B. Location in patent: Paragraph 0117

Methyl 2-Methyl-4-nitrobenzoate Preparation Products And Raw materials

Raw materials

Methyl 3-nitrophenylacetate Sodium Methoxide Methanol 2-Methyl-4-nitrobenzoic acid Iodomethane

2-Methyl-4-nitrobenzoyl chloride

1of2

Preparation Products

Methyl 2-Methyl-4-nitrobenzoate Suppliers

Global( 117)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
TCI (Shanghai) Development Co., Ltd.	021-67121386	Sales-CN@TCIchemicals.com	China	24512	81
Energy Chemical	400-0056266	sales8178@energy-chemical.com	China	44850	61
Jia Xing Isenchem Co.,Ltd	0573-85285100 18627885956	isenchem@163.com	China	9389	66
Accela ChemBio Co.,Ltd.	021-50795510 4000665055	marketing@accelachem.com	China	10972	64
Hangzhou Sage Chemical Co., Ltd.	+86057186818502 13588463833	info@sagechem.com	China	10265	58
Shanghai Topbiochem Technology Co., Ltd	021-58170097	info@topbiochem.com	China	9513	58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.	025-66113011 13913916777	cfzhang@aikonchem.com	China	19902	55
Shanghai Jian Chao Chemical Technology Co., Ltd.	150-2103-5486 18017383231	983544897@qq.com	China	9336	55
TOKYO CHEMICAL INDUSTRY CO., LTD.	03-36680489	Sales-JP@TCIchemicals.com	Japan	28364	80
TCI Europe	320-37350700	sales@tcieurope.eu	Europe	23654	75

Supplier	Advantage
TCI (Shanghai) Development Co., Ltd.	81
Energy Chemical	61
Jia Xing Isenchem Co.,Ltd	66
Accela ChemBio Co.,Ltd.	64
Hangzhou Sage Chemical Co., Ltd.	58
Shanghai Topbiochem Technology Co., Ltd	58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.	55
Shanghai Jian Chao Chemical Technology Co., Ltd.	55
TOKYO CHEMICAL INDUSTRY CO., LTD.	80
TCI Europe	75

View Lastest Price from Methyl 2-Methyl-4-nitrobenzoate manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2020-02-17	Methyl 2-Methyl-4-nitrobenzoate 62621-09-4	$1.00	1KG	99%	200kgs	Career Henan Chemical Co

Methyl 2-Methyl-4-nitrobenzoate
62621-09-4
$1.00
99%
Career Henan Chemical Co

Methyl 2-Methyl-4-nitrobenzoate Spectrum

Methyl 2-Methyl-4-nitrobenzoate(62621-09-4)¹HNMR

62621-09-4(Methyl 2-Methyl-4-nitrobenzoate)Related Search:

ETHYL 3-METHYL-4-NITROBENZOATE Methyl 5-Methyl-2-Nitrobenzoate Ethyl 3-bromo-4-methylbenzoate Methyl-5-amino-2-chlorobenzoate Ethyl 3-Amino-4-methylbenzoate

METHYL 2-AMINO-5-METHYLBENZOATE 7-Chloro-1-cyclopropyl-6-fluoro-1,4-dihydro-4-oxo-1,8-naphthyridine-3-carboxylic Acid Ethyl Ester Methyl 4-hydroxy-2-methylbenzoate ETHYL 2-AMINO-5-METHYLBENZOATE 4-AMINO-2-METHYLBENZOIC ACID ETHYL ESTER

Ethyl 2-methyl-3-nitrobenzoate METHYL 2-BROMO-5-METHYLBENZOATE 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER Methyl4-amino-2-methylbenzoate Ethyl 4-Bromo-3-methylbenzoate

Methyl 4-chloro-3-methylbenzoate Benzoic acid,4-bromo-2-methyl-,methyl ester 5-Amino-2-methyl-benzoic acid methyl ester

1of4

Methyl 2-Methyl-4-nitrobenzoate Benzoic acid, 2-Methyl-4-nitro-, Methyl ester Methyl 4-Nitro-2-Methylbenzoate 2-Methyl-4-nitrobenzoic acid methyl ester _x005f\rMethyl 2-Methyl-4-nitrobenzoate Methyl2-Methyl-4-nitrobenzoate> 4-Nitro-o-toluic Acid Methyl Ester Methyl 4-Nitro-o-toluate 2-Pyridinecarboxylicacid,7-(trifluoromethyl)- 62621-09-4 Esters Phenyls & Phenyl-Het