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Methyl 2-amino-5-methylbenzoate

Methyl 2-amino-5-methylbenzoate structure

CAS No.: 18595-16-9

Chemical Name:: Methyl 2-amino-5-methylbenzoate

Synonyms: NSC 3109;SunaroMe UVA;Methyl 6-Amino-m-toluate;o-(Methoxycarbonyl)aniline;Methyl 5-methylanthranilate;Methyl 2-amino-5-methylbenzoate;[2-(Methoxycarbonyl)phenyl]aMine;Methyl2-Amino-5-methylbenzoate>6-Amino-m-toluic Acid Methyl Ester;5-Methylanthranilic Acid Methyl Ester

CBNumber:: CB3454611

Molecular Formula:: C9H11NO2

Molecular Weight:: 165.19

MDL Number:: MFCD00661547

MOL File:: 18595-16-9.mol

MSDS File:: SDS

Last updated:2026-09-12 18:52:03

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Methyl 2-amino-5-methylbenzoate Properties

Melting point	54-56°C
Density	1.132
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
solubility	Dichloromethane, Ethyl Acetate, Methanol
form	Solid
color	Yellow to Brown

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319

Precautionary statements

P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

HS Code

2922498590

NFPA 704

	0
1		0

Methyl 2-amino-5-methylbenzoate price More Price(51)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TCI Chemical	M2541	Methyl 2-Amino-5-methylbenzoate >98.0%(GC)(T)	18595-16-9	5g	$56	2026-04-30	Buy
TCI Chemical	M2541	Methyl 2-Amino-5-methylbenzoate >98.0%(GC)(T)	18595-16-9	25g	$190	2026-04-30	Buy
TRC	TRC-M286885-5G	Methyl 2-Amino-5-methylbenzoate	18595-16-9	5g	$65	2026-06-03	Buy
TRC	TRC-M286885-25G	Methyl 2-Amino-5-methylbenzoate	18595-16-9	25g	$142	2026-06-03	Buy
TRC	TRC-M286885-10G	Methyl 2-Amino-5-methylbenzoate	18595-16-9	10g	$84	2026-06-03	Buy

Product number	Packaging	Price	Buy
M2541	5g	$56	Buy
M2541	25g	$190	Buy
TRC-M286885-5G	5g	$65	Buy
TRC-M286885-25G	25g	$142	Buy
TRC-M286885-10G	10g	$84	Buy

Methyl 2-amino-5-methylbenzoate Chemical Properties, Uses, Production

Chemical Properties

METHYL 2-AMINO-5-METHYLBENZOATE is yellow Solid

Uses

METHYL 2-AMINO-5-METHYLBENZOATE is a useful synthetic intermediate

Uses

A useful synthetic intermediate.

Synthesis

20587-30-8

18595-16-9

Methyl 5-methyl-2-nitrobenzoate (8 g, 41.025 mmol) was used as a raw material in a solvent mixture of methanol (80 mL) and water (10 mL), and cooled to 0 °C. Subsequently, zinc powder (13.33 g, 205.128 mmol) and NH4Cl (17.6 g, 328.2 mmol) were added sequentially. The reaction mixture was stirred at room temperature for 12 h. The reaction progress was monitored by TLC (unfolding agent: 20% ethyl acetate/hexane). After completion of the reaction, the mixture was filtered and the filtrate was evaporated to give the crude product. The crude product was alkalized with saturated NaHCO3 solution and extracted with dichloromethane (2 x 20 mL). The organic layers were combined, dried with Na2SO4, filtered and the solvent was evaporated to give the target compound methyl 2-amino-5-methylbenzoate (yield: 4 g, 60%).1H NMR (400 MHz, CDCl3) data were as follows: δ 7.65 (s, 1H), 7.25 (s, 1H), 7.10-7.07 (q, 1H, J=8Hz), 6.58 (d, 1H), 3.86 (s, 3H), 2.22 (s, 3H).

References

[1] Patent: WO2015/38417, 2015, A1. Location in patent: Paragraph 151; 152
[2] Journal of the Chemical Society, 1930, p. 1513,1516
[3] Bioorganic and Medicinal Chemistry Letters, 2009, vol. 19, # 15, p. 4416 - 4420
[4] Patent: EP1475368, 2004, A1. Location in patent: Page 57

Methyl 2-amino-5-methylbenzoate Preparation Products And Raw materials

Raw materials

Methanol Methyl 5-Methyl-2-Nitrobenzoate 2-Amino-5-methylbenzoic acid ZINC Water

Ammonium chloride

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Preparation Products

Methyl 2-bromo-5-methylbenzoate

Methyl 2-amino-5-methylbenzoate Suppliers

Global Suppliers ( 133)

Supplier	Tel	Email	Country	ProdList	Advantage
J & K SCIENTIFIC LTD.	18210857532 18210857532	jkinfo@jkchemical.com	China	96815	76
3B Pharmachem (Wuhan) International Co.,Ltd.	18930552037	3bsc@sina.com	China	15813	69
TCI (Shanghai) Development Co., Ltd.	021-67121386	Sales-CN@TCIchemicals.com	China	24512	81
Energy Chemical	400-0056266	sales8178@energy-chemical.com	China	44850	61
Jia Xing Isenchem Co.,Ltd	0573-85285100 18627885956	isenchem@163.com	China	9389	66
Accela ChemBio Co.,Ltd.	021-50795510 4000665055	marketing@accelachem.com	China	10972	64
Nanjing Chemlin Chemical Co., Ltd	025-83697070 13770331960	info@chemlin.com.cn	China	16305	64
Shanghai Hanhong Scientific Co.,Ltd.	021-54306202 13764082696	info@hanhongsci.com	China	42917	64
Chemsky（shanghai）International Co.,Ltd.	021-50135380	shchemsky@sina.com	China	32273	50
Beijing Isomersyn Technology CO;LTD	010-82954736 13391601435	sales@isomersyn.com	China	3294	57

Supplier	Advantage
J & K SCIENTIFIC LTD.	76
3B Pharmachem (Wuhan) International Co.,Ltd.	69
TCI (Shanghai) Development Co., Ltd.	81
Energy Chemical	61
Jia Xing Isenchem Co.,Ltd	66
Accela ChemBio Co.,Ltd.	64
Nanjing Chemlin Chemical Co., Ltd	64
Shanghai Hanhong Scientific Co.,Ltd.	64
Chemsky（shanghai）International Co.,Ltd.	50
Beijing Isomersyn Technology CO;LTD	57

View Latest Price from Methyl 2-amino-5-methylbenzoate manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2020-01-10	METHYL 2-AMINO-5-METHYLBENZOATE 18595-16-9	$9.80	1g	≥99%	100kg	Career Henan Chemical Co
	2019-07-14	METHYL 2-AMINO-5-METHYLBENZOATE 18595-16-9	$1.00	1KG	99%	100kg	Career Henan Chemical Co

METHYL 2-AMINO-5-METHYLBENZOATE
18595-16-9
$9.80
≥99%
Career Henan Chemical Co

METHYL 2-AMINO-5-METHYLBENZOATE
18595-16-9
$1.00
99%
Career Henan Chemical Co

Methyl 2-amino-5-methylbenzoate Spectrum

METHYL 2-AMINO-5-METHYLBENZOATE(18595-16-9)¹HNMR METHYL 2-AMINO-5-METHYLBENZOATE(18595-16-9)FT-IR

18595-16-9 (Methyl 2-amino-5-methylbenzoate) Related Search:

5-Amino-2-methyl-benzoic acid methyl ester Benzoic acid,4-bromo-2-methyl-,methyl ester Methyl 4-chloro-3-methylbenzoate Ethyl 4-Bromo-3-methylbenzoate Ethyl 4-Hydroxy-2-Methylbenzoate

Methyl4-amino-2-methylbenzoate Methyl 5-Methyl-2-Nitrobenzoate Ethyl 3-bromo-4-methylbenzoate Methyl-5-amino-2-chlorobenzoate Ethyl 3-Amino-4-methylbenzoate

7-Chloro-1-cyclopropyl-6-fluoro-1,4-dihydro-4-oxo-1,8-naphthyridine-3-carboxylic Acid Ethyl Ester Methyl 4-hydroxy-2-methylbenzoate Methyl 2-Methyl-4-nitrobenzoate Ethyl 2-methyl-3-nitrobenzoate Ethyl 3-methyl-4-nitrobenzoate

Ethyl 2-amino-5-methylbenzoate 3-Bromo-2-methyl-benzoic acid methyl ester 4-Amino-2-methylbenzoic acid ethyl ester

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Methyl 5-methylanthranilate [2-(Methoxycarbonyl)phenyl]aMine NSC 3109 o-(Methoxycarbonyl)aniline SunaroMe UVA 5-Methyl-2-aMinobenzoic acid Methyl ester 2-Amino-5-methylbenzoic acid methyl ester Methyl2-Amino-5-methylbenzoate> Benzoic acid, 2-amino-5-methyl-, methyl ester 5-Methylanthranilic Acid Methyl Ester 6-Amino-m-toluic Acid Methyl Ester Methyl 6-Amino-m-toluate Methyl 2-amino-5-methylbenzoate 18595-16-9 8595-16-9 Aromatics Compounds Aromatics