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Methyl 2-bromo-5-methylbenzoate

Methyl 2-bromo-5-methylbenzoate Structure
Methyl 2-bromo-5-methylbenzoate structure
CAS No.
90971-88-3
Chemical Name:
Methyl 2-bromo-5-methylbenzoate
Synonyms
Methyl 2-bromo-5-methylbenzoate;Benzoic acid, 2-broMo-5-Methyl-, Methyl ester
CBNumber:
CB1107601
Molecular Formula:
C9H9BrO2
Molecular Weight:
229.07
MDL Number:
MFCD00144764
MOL File:
90971-88-3.mol
MSDS File:
SDS
Last updated:2026-09-12 18:48:34
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Methyl 2-bromo-5-methylbenzoate Properties

Boiling point 270.1±20.0 °C(Predicted)
Density 1.433±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
Appearance Colorless to light yellow Liquid
InChI InChI=1S/C9H9BrO2/c1-6-3-4-8(10)7(5-6)9(11)12-2/h3-5H,1-2H3
InChIKey PYRAZCQFEMNXJA-UHFFFAOYSA-N
SMILES C(OC)(=O)C1=CC(C)=CC=C1Br

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Flame (GHS02)
GHS07,GHS02
Signal word  Warning
Hazard statements  H315-H319-H226
Precautionary statements  P501-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P337+P313-P305+P351+P338-P362+P364-P303+P361+P353-P332+P313-P403+P235
HS Code  2916399090

Methyl 2-bromo-5-methylbenzoate price More Price(56)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Apolloscientific OR315327 Methyl 2-bromo-5-methylbenzoate >98% 90971-88-3 5g $21 2026-06-04 Buy
Activate Scientific AS85099 2-Bromo-5-methylbenzoic acid methyl ester 97% 90971-88-3 1g $22 2026-06-04 Buy
Activate Scientific AS85099 2-Bromo-5-methylbenzoic acid methyl ester 97% 90971-88-3 5g $33 2026-06-04 Buy
Apolloscientific OR315327 Methyl 2-bromo-5-methylbenzoate >98% 90971-88-3 25g $55 2026-06-04 Buy
Activate Scientific AS85099 2-Bromo-5-methylbenzoic acid methyl ester 97% 90971-88-3 25g $65 2026-06-04 Buy
Product number Packaging Price Buy
OR315327 5g $21 Buy
AS85099 1g $22 Buy
AS85099 5g $33 Buy
OR315327 25g $55 Buy
AS85099 25g $65 Buy

Methyl 2-bromo-5-methylbenzoate Chemical Properties,Uses,Production

Synthesis

Methanol

67-56-1

2-BROMO-5-METHYLBENZOIC ACID

6967-82-4

METHYL 2-BROMO-5-METHYLBENZOATE

90971-88-3

Step 1: Preparation of methyl 2-bromo-5-methylbenzoate Oxalyl chloride (0.13 mL, 1.5 mmol) was slowly added to a mixed solution of dichloromethane (DCM, 4 mL) and N,N-dimethylformamide (DMF, 1 drop) of 2-bromo-5-methylbenzoic acid (215 mg, 1.0 mmol) at 0 °C. The reaction mixture was stirred at room temperature for 1 hour before oxalyl chloride (0.13 mL, 1.5 mmol) was added again. After continued stirring for 1 hour, methanol (MeOH, 2 mL) was added and the reaction mixture continued to stir for 6 hours. Upon completion of the reaction, the pH was adjusted to 9 with sodium carbonate (Na2CO3) solution and extracted with dichloromethane (DCM, 2 x 10 mL). The organic layers were combined, washed with saturated saline, dried over anhydrous sodium sulfate (Na2SO4), filtered and concentrated under reduced pressure. The crude product was purified by silica gel column chromatography to afford methyl 2-bromo-5-methylbenzoate (210 mg, 92% yield) as a colorless oil using petroleum ether-ethyl acetate (PE-EA, 15:1) as eluent. 1H NMR (400 MHz, CDCl3): δ 7.60 (d, J = 1.6 Hz, 1H), 7.53 (d, J = 8.8 Hz, 1H), 7.15 (q, J = 3.2 Hz, 1H), 3.92 (s, 3H), 2.33 (s, 3H) ppm.

References

[1] Tetrahedron, 2014, vol. 70, # 14, p. 2383 - 2388
[2] Patent: CN105461699, 2016, A. Location in patent: Paragraph 0739; 0740; 0741; 0742; 0743
[3] Patent: WO2013/9259, 2013, A1. Location in patent: Page/Page column 90; 91
[4] Patent: WO2013/36196, 2013, A1. Location in patent: Page/Page column 95
[5] Patent: US2013/131016, 2013, A1. Location in patent: Paragraph 0199

Methyl 2-bromo-5-methylbenzoate synthesis

67-56-1
6967-82-4
90971-88-3
Synthesis of Methyl 2-bromo-5-methylbenzoate from Methanol and 2-Bromo-5-methylbenzoic acid

Methyl 2-bromo-5-methylbenzoate Preparation Products And Raw materials

Raw materials

2-Bromo-5-methylbenzoic acid Methyl 2-amino-5-methylbenzoate 2-Amino-5-methylbenzoic acid N,N-Dimethylformamide Methanol
(Trimethylsilyl)diazomethane Dichloromethane Oxalyl chloride

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Preparation Products

6(5H)-Phenanthridinone, 8-methyl-

Methyl 2-bromo-5-methylbenzoate Suppliers

Global( 92)Suppliers
Supplier Tel Email Country ProdList Advantage
Xinyi Kangda Biological Technology Co., Ltd. 16503038585 xinyikangda@163.com China 610 58
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Beijing Isomersyn Technology CO;LTD 010-82954736 13391601435 sales@isomersyn.com China 3294 57
Hangzhou Sage Chemical Co., Ltd. +86057186818502 13588463833 info@sagechem.com China 10265 58
9ding chemical ( Shanghai) Limited 4009209199 sales@9dingchem.com China 18201 56
Shanghai Raise Chemical Technology Co.,Ltd +86-021-50935922 China 7854 55
Amatek Scientific Co. Ltd. 0512-56316828 4008675858 sales@amateksci.com China 9849 55
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Cool Pharm, Ltd 021-60455363 18019463053 sales@coolpharm.com China 8455 58
DebyeTec.com Inc. 18086626237 18086626237 2693528373@qq.com China 2937 56
Supplier Advantage
Xinyi Kangda Biological Technology Co., Ltd. 58
Energy Chemical 61
Beijing Isomersyn Technology CO;LTD 57
Hangzhou Sage Chemical Co., Ltd. 58
9ding chemical ( Shanghai) Limited 56
Shanghai Raise Chemical Technology Co.,Ltd 55
Amatek Scientific Co. Ltd. 55
Bide Pharmatech Ltd. 60
Cool Pharm, Ltd 58
DebyeTec.com Inc. 56

View Lastest Price from Methyl 2-bromo-5-methylbenzoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
METHYL 2-BROMO-5-METHYLBENZOATE pictures 2026-07-30 METHYL 2-BROMO-5-METHYLBENZOATE
90971-88-3
 1KG 99% 1000kgs Shaanxi Dideu New Materials Co. Ltd
METHYL 2-BROMO-5-METHYLBENZOATE pictures 2020-02-19 METHYL 2-BROMO-5-METHYLBENZOATE
90971-88-3
 $1.00 1KG 99% 200kgs Career Henan Chemical Co

Methyl 2-bromo-5-methylbenzoate Spectrum

METHYL 2-BROMO-5-METHYLBENZOATE(90971-88-3)1HNMR

90971-88-3(Methyl 2-bromo-5-methylbenzoate)Related Search:

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Benzoic acid, 2-broMo-5-Methyl-, Methyl ester Methyl 2-bromo-5-methylbenzoate 90971-88-3 Acids & Esters Bromine Compounds