3-Bromo-2-methyl-benzoic acid methyl ester
- CAS No.
- 99548-54-6
- Chemical Name:
- 3-Bromo-2-methyl-benzoic acid methyl ester
- Synonyms
- METHYL 3-BROMO-2-METHYLBENZOATE;Methyl 3-Bromo-o-toluate;3-BroMo-o-toluic Acid Methyl Ester;Methyl 3-bromo-2-methylbenzoate 97%;3-BroMo-2-Methyl-benzoic acid Methy;3-Bromo-2-methyl-benzoic acid methyl ester;Benzoic acid, 3-broMo-2-Methyl-, Methyl ester;Methyl 3-bromo-o-toluate, 2-Bromo-6-(methoxycarbonyl)toluene;Methyl 3-bromo-2-methylbenzoate , Methyl 3-bromo-2-methylbenzoate
- CBNumber:
- CB7847693
- Molecular Formula:
- C9H9BrO2
- Molecular Weight:
- 229.07
- MDL Number:
- MFCD09031772
- MOL File:
- 99548-54-6.mol
- MSDS File:
- SDS
| Melting point | 29 °C |
|---|---|
| Boiling point | 140°C/21mmHg(lit.) |
| Density | 1.433±0.06 g/cm3(Predicted) |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Chloroform |
| form | Solid |
| color | White |
| InChI | InChI=1S/C9H9BrO2/c1-6-7(9(11)12-2)4-3-5-8(6)10/h3-5H,1-2H3 |
| InChIKey | MKQQTCSBXHAYQL-UHFFFAOYSA-N |
| SMILES | C(OC)(=O)C1=CC=CC(Br)=C1C |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319 | |||||||||
| Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 | |||||||||
| HS Code | 2916399090 | |||||||||
| NFPA 704 |
|
3-Bromo-2-methyl-benzoic acid methyl ester price More Price(68)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | M2543 | Methyl 3-Bromo-2-methylbenzoate >98.0%(GC) | 99548-54-6 | 5g | $88 | 2026-04-30 | Buy |
| TCI Chemical | M2543 | Methyl 3-Bromo-2-methylbenzoate >98.0%(GC) | 99548-54-6 | 25g | $262 | 2026-04-30 | Buy |
| Biosynth | FB19099 | 3-Bromo-2-methylbenzoic acid methyl ester | 99548-54-6 | 0.25kg | $900 | 2026-06-04 | Buy |
| Biosynth | FB19099 | 3-Bromo-2-methylbenzoic acid methyl ester | 99548-54-6 | 0.1kg | $900 | 2026-06-04 | Buy |
| Biosynth | FB19099 | 3-Bromo-2-methylbenzoic acid methyl ester | 99548-54-6 | 0.05kg | $900 | 2026-06-04 | Buy |
3-Bromo-2-methyl-benzoic acid methyl ester Chemical Properties,Uses,Production
Uses
3-Bromo-2-methylbenzoic Acid Methyl Ester is a compound useful in organic synthesis.
Chemical Properties
White Solid
Synthesis
76006-33-2
74-88-4
99548-54-6
3-Bromo-2-methylbenzoic acid (16 g, 74.4 mmol) and iodomethane (21.2 g, 148.8 mmol) were reacted in DMF (160 mL) in the presence of sodium bicarbonate (12.5 g, 148.8 mmol). The reaction mixture was heated and stirred at 60 °C for 2 hours. After the reaction was completed, the mixture was cooled to room temperature and slowly poured into ice water (400 mL). The aqueous phase was extracted with ethyl acetate (4 x 100 mL) and the organic phases were combined. The organic phase was washed sequentially with water (3 x 100 mL) and saturated saline (100 mL) and then dried with anhydrous magnesium sulfate. The solvent was removed by concentration under reduced pressure to give methyl 3-bromo-2-methylbenzoate (17.6 g, 100% yield) as an oil. The product was characterized by 1H NMR (CDCl3): δ 7.70 (t, J = 7.6 Hz, 2H), 7.08 (t, J = 7.9 Hz, 1H), 3.90 (s, 3H), 2.67 (s, 3H).
References
[1] Patent: US2003/96841, 2003, A1
[2] Patent: US2014/179667, 2014, A1. Location in patent: Paragraph 0802; 0803
[3] Patent: WO2008/65199, 2008, A1. Location in patent: Page/Page column 74
3-Bromo-2-methyl-benzoic acid methyl ester Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Dalian lichuang Chemical Co., Ltd | 0411-0411-00000000 13644282108 | 3500508746@qq.com | China | 2942 | 55 |
| Zhengzhou Haode Pharmaceutical Technology Co.,Ltd | 18037386321 | 3330511471@qq.com | China | 498 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Beijing Ouhe Technology Co., Ltd | 13552068683 13522913783 | 2355560935@qq.com | China | 11777 | 60 |
| Jia Xing Isenchem Co.,Ltd | 0573-85285100 18627885956 | isenchem@163.com | China | 9389 | 66 |
| Tetranov Biopharm | 13526569071 | sales@leadmedpharm.com | China | 7882 | 64 |
| Accela ChemBio Co.,Ltd. | 021-50795510 4000665055 | marketing@accelachem.com | China | 10972 | 64 |
| Shanghai Harvest Chemical Industrial Co., Ltd. | 15721252604 17321035817 | sales@harvest-chem.com | China | 2829 | 64 |
View Lastest Price from 3-Bromo-2-methyl-benzoic acid methyl ester manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-05-18 | 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER
99548-54-6
|
1kg | 98% | Hefei Lbao Physical & Chemical Science Co.,Ltd | |||
 |
2020-01-13 | 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER
99548-54-6
|
$1.00 | 1g | 99% | 10000KGS | Career Henan Chemical Co |
-
- 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER
99548-54-6
- $0.00
- 98%
- Hefei Lbao Physical & Chemical Science Co.,Ltd
-
- 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER
99548-54-6
- $1.00
- 99%
- Career Henan Chemical Co
99548-54-6(3-Bromo-2-methyl-benzoic acid methyl ester)Related Search:
1of4
