trans-1,4-Cyclohexanedicarboxylic acid monomethyl ester
- CAS No.
- 15177-67-0
- Chemical Name:
- trans-1,4-Cyclohexanedicarboxylic acid monomethyl ester
- Synonyms
- TRANS-4-(METHOXYCARBONYL)CYCLOHEXANECARBOXYLIC ACID;trans-4-(Methoxycarbonyl);Monmethyl trans-1,4-cyclohexanedicarboxylate;MonoMethyl trans-1,4-cyclohexanedicarboxylate;Methyl trans-4-carboxycyclohexane-1-carboxylate;4(METHOXY CARBONYL) CYCLOHEXANE CARBOXYLIC ACID;4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL ESTER;TRANS-1,4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL;TRANS-4-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID;Monomethyl trans-1,4-Cyclohexanedicarboxylate >
- CBNumber:
- CB5363218
- Molecular Formula:
- C9H14O4
- Molecular Weight:
- 186.21
- MDL Number:
- MFCD01311247
- MOL File:
- 15177-67-0.mol
- MSDS File:
- SDS
| Melting point | 126.0 to 130.0 °C |
|---|---|
| Boiling point | 303.1±35.0 °C(Predicted) |
| Density | 1.191±0.06 g/cm3(Predicted) |
| storage temp. | Sealed in dry,Room Temperature |
| form | powder to crystal |
| pka | 4.66±0.10(Predicted) |
| color | White to Almost white |
| InChI | InChI=1S/C9H14O4/c1-13-9(12)7-4-2-6(3-5-7)8(10)11/h6-7H,2-5H2,1H3,(H,10,11)/t6-,7- |
| InChIKey | ZQJNPHCQABYENK-LJGSYFOKSA-N |
| SMILES | [C@@H]1(C(OC)=O)CC[C@@H](C(O)=O)CC1 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H315-H319-H335 | |||||||||
| Precautionary statements | P260-P280-P312 | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36/37/39 | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 2917200090 | |||||||||
| NFPA 704 |
|
trans-1,4-Cyclohexanedicarboxylic acid monomethyl ester price More Price(62)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | M2526 | Monomethyl trans-1,4-Cyclohexanedicarboxylate >97.0%(GC)(T) | 15177-67-0 | 5g | $56 | 2026-04-30 | Buy |
| TCI Chemical | M2526 | Monomethyl trans-1,4-Cyclohexanedicarboxylate >97.0%(GC)(T) | 15177-67-0 | 25g | $190 | 2026-04-30 | Buy |
| Usbiological | 290693 | Trans-1,4-cyclohexane dicarboxylic acid monomethyl ester Asreported | 15177-67-0 | 5g | $342 | 2026-06-03 | Buy |
| Usbiological | 290693 | Trans-1,4-cyclohexane dicarboxylic acid monomethyl ester Asreported | 15177-67-0 | 10g | $470 | 2026-06-03 | Buy |
| Usbiological | 290693 | Trans-1,4-cyclohexane dicarboxylic acid monomethyl ester Asreported | 15177-67-0 | 25g | $632 | 2026-06-03 | Buy |
trans-1,4-Cyclohexanedicarboxylic acid monomethyl ester Chemical Properties,Uses,Production
Uses
Trans-cyclohexane-1,4-dicarboxylic acid monomethyl ester is a carboxylic acid ester derivative, used as organic reagents.
Synthesis
94-60-0
15177-67-0
(1) Isomerization reaction: 0.5 mol (100.1 g) of dimethyl 1,4-cyclohexanedicarboxylate (Ib) with a trans/cis isomer ratio of 3/7 to 5/5 was dissolved in 200 g of methanol at 40°C. The reaction was carried out by adding 15 g of pyridine as a catalyst. 15 g of pyridine was added as a catalyst, and after 2 h of reaction, a methanolic solution of dimethyl 1,4-cyclohexanedicarboxylate (II-b) with a trans/cis isomer ratio of 9/1 was obtained. (2) Monoester hydrolysis reaction: The methanol solution of dimethyl 1,4-cyclohexanedicarboxylate (II-b) with a trans/cis isomer ratio of 9/1 obtained in step (1) was cooled to room temperature, and 150 g of potassium hydroxide was added. The reaction was carried out at 20°C for 3 h. Monoester hydrolysis was carried out to obtain a water-soluble carboxylic acid ester of trans-1,4-cyclohexanedicarboxylic acid monomethyl ester. (3) Acidification and post-treatment: 200 g of water and 100 g of toluene were added to the reaction system of step (2), and the organic phase was removed by extraction and stratification. The aqueous phase was adjusted to pH 1-2 with concentrated hydrochloric acid and the mixture was cooled to 0 °C. After filtration, the mixture was dried under reduced pressure at 50 °C to afford 66.4 g of white solid powder of monomethyl trans-1,4-cyclohexanedicarboxylate (III). The yield was 71.32% and the purity of compound (III) was 98.9% as determined by gas chromatography.
References
[1] Patent: CN108129307, 2018, A. Location in patent: Paragraph 0027-0041
trans-1,4-Cyclohexanedicarboxylic acid monomethyl ester Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Targsense Scientific Co., Ltd. | 18916626092 | targsense@qq.com | China | 110 | 65 |
| Chongqing Acemol Technology Co.,Ltd | 023-86822659 18611316925 | sales@acemol.com | China | 991 | 55 |
| Tocopharm Co., Ltd. | +86-021-69895597 13776836200 +86-13776836200 | tocopharm@gmail.com | China | 207 | 55 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| INTATRADE GmbH | +49 3493/605464 | sales@intatrade.de | Germany | 3563 | 66 |
| ChemFuture PharmaTech (Jiangsu) Ltd | 5108538618 | suger.wang@chemfuture.com | China | 832 | 65 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Beijing Ouhe Technology Co., Ltd | 13552068683 13522913783 | 2355560935@qq.com | China | 11777 | 60 |
View Lastest Price from trans-1,4-Cyclohexanedicarboxylic acid monomethyl ester manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-06-30 | TRANS-1,4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL ESTER
15177-67-0
|
1kg | 99% | 10000KGS | Shaanxi Dideu New Materials Co. Ltd | ||
 |
2025-04-04 | TRANS-1,4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL ESTER
15177-67-0
|
1KG | 98% | 1ton | Henan Aochuang Chemical Co.,Ltd. | ||
 |
2022-02-09 | Trans-1,4-cyclohexanedicarboxylic acid monomethyl ester
15177-67-0
|
1KG | 98.0% | 100 tons | Honest Joy Holdings Limited |
-
- TRANS-1,4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL ESTER
15177-67-0
- $0.00
- 99%
- Shaanxi Dideu New Materials Co. Ltd
-
- TRANS-1,4-CYCLOHEXANEDICARBOXYLIC ACID MONOMETHYL ESTER
15177-67-0
- 98%
- Henan Aochuang Chemical Co.,Ltd.
-
- Trans-1,4-cyclohexanedicarboxylic acid monomethyl ester
15177-67-0
- $0.00
- 98.0%
- Honest Joy Holdings Limited
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