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5-AMINO-3-BROMO-2-METHYLPYRIDINE

5-AMINO-3-BROMO-2-METHYLPYRIDINE structure

CAS No.: 186593-43-1

Chemical Name:: 5-AMINO-3-BROMO-2-METHYLPYRIDINE

Synonyms: 5-Bromo-6-methylpyridin-3-amine;5-AMINO-3-BROMO-2-PICOLINE;3-Bromo-5-Amino-2-Picoline;5-Amino-3-bromo-2-methylp...;5-Bromo-6-methyl-3-pyridinamine;5-Amino-3-Bromo-2-methylpyridin;2-Methyl-3-broMo-5-aMinopyridine;5-AMINO-3-BROMO-2-METHYLPYRIDINE;3-Pyridinamine, 5-bromo-6-methyl-;5-aminio-3-bromo-2-methylpyridine

CBNumber:: CB5841596

Molecular Formula:: C6H7BrN2

Molecular Weight:: 187.04

MDL Number:: MFCD08060462

MOL File:: 186593-43-1.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-05-28 04:50:19

Product description	Number	Pack Size	Price
5-Amino-3-bromo-2-methylpyridine >98.0%(GC)(T)	A2996	1g	$159
5-Amino-3-bromo-2-methylpyridine >98.0%(GC)(T)	A2996	5g	$494
5-Amino-3-bromo-2-methylpyridine >98%	OR315100	1g	$21
5-Amino-3-bromo-2-methylpyridine >98%	OR315100	5g	$33
5-Amino-3-bromo-2-methylpyridine >98%	OR315100	25g	$139
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5-AMINO-3-BROMO-2-METHYLPYRIDINE Properties

Melting point	103.0 to 108.0 °C
Boiling point	281.3±35.0 °C(Predicted)
Density	1.593±0.06 g/cm3(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2–8 °C
form	powder to crystal
pka	4.53±0.20(Predicted)
color	White to Brown
InChI	InChI=1S/C6H7BrN2/c1-4-6(7)2-5(8)3-9-4/h2-3H,8H2,1H3
InChIKey	UCLLYIVDXZGQSZ-UHFFFAOYSA-N
SMILES	C1=NC(C)=C(Br)C=C1N

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H302-H315-H319-H335

Precautionary statements

P271-P261-P280

HS Code

2933399990

NFPA 704

	0
2		0

5-AMINO-3-BROMO-2-METHYLPYRIDINE price More Price(62)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TCI Chemical	A2996	5-Amino-3-bromo-2-methylpyridine >98.0%(GC)(T)	186593-43-1	1g	$159	2026-04-30	Buy
TCI Chemical	A2996	5-Amino-3-bromo-2-methylpyridine >98.0%(GC)(T)	186593-43-1	5g	$494	2026-04-30	Buy
Apolloscientific	OR315100	5-Amino-3-bromo-2-methylpyridine >98%	186593-43-1	1g	$21	2026-06-04	Buy
Apolloscientific	OR315100	5-Amino-3-bromo-2-methylpyridine >98%	186593-43-1	5g	$33	2026-06-04	Buy
Apolloscientific	OR315100	5-Amino-3-bromo-2-methylpyridine >98%	186593-43-1	25g	$139	2026-06-04	Buy

Product number	Packaging	Price	Buy
A2996	1g	$159	Buy
A2996	5g	$494	Buy
OR315100	1g	$21	Buy
OR315100	5g	$33	Buy
OR315100	25g	$139	Buy

5-AMINO-3-BROMO-2-METHYLPYRIDINE Chemical Properties,Uses,Production

Uses

5-Amino-3-bromo-2-methylpyridine is a versatile reactant used in different synthetic preparations. It was used in the synthesis of amino acids by asymmetric enzymic transamination of keto acids in presence of axially chiral pyridoxamines as catalysts.

Synthesis

1190862-72-6

186593-43-1

The general procedure for the synthesis of 2-methyl-3-bromo-5-aminopyridine from 5-bromo-6-methylnicotinic acid was as follows: 5-bromo-6-methylpyridine-3-carboxylic acid (1 g, 4.63 mmol) was dissolved in a solvent mixture of tert-butanol (6.6 mL) and N,N-dimethylformamide (15 mL), followed by triethylamine (5.15 mL, 37.04 mmol) and diphenylphosphoryl azide (0.51 mL, 5.093 mmol). The reaction mixture was heated to 100°C and stirred for 2 hours. Upon completion of the reaction, the progress was monitored by thin layer chromatography (TLC). The solvent was evaporated to dryness and the residue was dissolved in saturated sodium bicarbonate solution and extracted with ethyl acetate. The organic phase was dried over anhydrous sodium sulfate and filtered and the solvent was evaporated to dryness. The residue was purified by silica gel column chromatography to give a white solid. The white solid was dissolved in dichloromethane (10 mL), a dioxane solution of 4N HCl was added and stirred for 2 hours at room temperature. Upon completion of the reaction, the solvent was evaporated to dryness to give 5-bromo-6-methylpyridin-3-ylamine (white solid, 130 mg).

References

[1] Patent: CN103420977, 2016, B. Location in patent: Paragraph 0293-0296

5-AMINO-3-BROMO-2-METHYLPYRIDINE synthesis

Synthesis of 5-AMINO-3-BROMO-2-METHYLPYRIDINE from 5-BroMo-6-Methylnicotinicacid

5-AMINO-3-BROMO-2-METHYLPYRIDINE Preparation Products And Raw materials

Raw materials

3-Bromo-2-chloro-5-nitropyridine 5-BroMo-6-Methylnicotinicacid 2,3-DIBROMO-5-NITRO PYRIDINE 3-Bromo-2-hydroxy-5-nitropyridine 3-BROMO-2-METHYL-5-NITROPYRIDINE

2-Hydroxy-5-nitropyridine Iron Triethylamine Diphenylphosphoryl azide tert-Butanol

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Preparation Products

5-AMINO-3-BROMO-2-METHYLPYRIDINE Suppliers

Global( 142)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29766	58
Accela ChemBio Inc.	+1-858-6993322 +86-18019713315	info@accelachem.com	United States	21189	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63645	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	+8613580539051	joe@yuhengpharm.com	CHINA	21135	58
Win-Win chemical CO., Limited	+86-0086-577-64498589 +86-15355981851	sales@win-winchemical.com	China	14301	58
Shanxi Xuanran Import and Export Trade Co., Ltd.	+8617735180244	mike_yan@xuanranglobal.com	CHINA	4011	58
ANHUI WITOP BIOTECH CO., LTD	+8618071025641	eric@witopchemical.com	China	23506	58
Dideu Industries Group Limited	+86-29-89586680 +86-15129568250	1059@dideu.com	China	29096	58
Hefei Hirisun Pharmatech Co., Ltd	+8615056975894	shawn@hirisunpharm.com	CHINA	9897	58
Dayang Chem (Hangzhou) Co.,Ltd.	+86-0571-88938639 17705817739	info@dycnchem.com	China	52693	58

Supplier	Advantage
career henan chemical co	58
Accela ChemBio Inc.	58
Alchem Pharmtech,Inc.	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	58
Win-Win chemical CO., Limited	58
Shanxi Xuanran Import and Export Trade Co., Ltd.	58
ANHUI WITOP BIOTECH CO., LTD	58
Dideu Industries Group Limited	58
Hefei Hirisun Pharmatech Co., Ltd	58
Dayang Chem (Hangzhou) Co.,Ltd.	58

View Lastest Price from 5-AMINO-3-BROMO-2-METHYLPYRIDINE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2025-11-18	5-AMINO-3-BROMO-2-METHYLPYRIDINE 186593-43-1	$1.10	1g	99.00%	100 Tons min	Dideu Industries Group Limited
	2019-07-06	5-AMINO-3-BROMO-2-METHYLPYRIDINE 186593-43-1	$1.00	1kg	98%	200KG	Career Henan Chemical Co

5-AMINO-3-BROMO-2-METHYLPYRIDINE
186593-43-1
$1.10
99.00%
Dideu Industries Group Limited

5-AMINO-3-BROMO-2-METHYLPYRIDINE
186593-43-1
$1.00
98%
Career Henan Chemical Co

5-AMINO-3-BROMO-2-METHYLPYRIDINE Spectrum

5-AMINO-3-BROMO-2-METHYLPYRIDINE(186593-43-1)¹HNMR

186593-43-1(5-AMINO-3-BROMO-2-METHYLPYRIDINE)Related Search:

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5-AMINO-3-BROMO-2-METHYLPYRIDINE 3-Bromo-5-Amino-2-Picoline 2-Methyl-3-broMo-5-aMinopyridine 5-Amino-3-bromo-2-methylp... 5-Bromo-6-methyl-3-pyridinamine 3-PyridinaMine, 5-broMo-2-chloro-6-Methyl- 5-BroMo-6-Methyl-pyridin-3-ylaMine 5-AMINO-3-BROMO-2-PICOLINE 5-aminio-3-bromo-2-methylpyridine 5-Amino-3-Bromo-2-methylpyridin 3-Pyridinamine, 5-bromo-6-methyl- 5-AMINO-3-BROMO-2-METHYLPYRIDINE ISO 9001：2015 REACH 5-Bromo-6-methylpyridin-3-amine 186593-43-1 Heterocycle-Pyridine series Amines Pyridines