ChemicalBook >> CAS DataBase List >>2-BROMO-5-METHYLBENZOIC ACID

2-BROMO-5-METHYLBENZOIC ACID

2-BROMO-5-METHYLBENZOIC ACID structure

CAS No.: 6967-82-4

Chemical Name:: 2-BROMO-5-METHYLBENZOIC ACID

Synonyms: NSC20686;Fluralaner-031;6-Bromo-m-toluic Acid;Fluralaner Impurity 52;2-Bromo-5-methylbenzoicaci;2-BROMO-5-METHYLBENZOIC ACID;Benzoic acid,2-bromo-5-methyl-;2-Bromo-5-methylbenzoicacid,98%;2-Bromo-5-methylbenzoic Acid >2-BroMo-5-Methylbenzoic Acid, 97+%

CBNumber:: CB6342232

Molecular Formula:: C8H7BrO2

Molecular Weight:: 215.04

MDL Number:: MFCD00079722

MOL File:: 6967-82-4.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-05-28 06:05:53

Product description	Number	Pack Size	Price
2-Bromo-5-methylbenzoic acid 97%	716413	1g	$55.9
2-Bromo-5-methylbenzoic Acid >98.0%(GC)(T)	B4145	5g	$22
2-Bromo-5-methylbenzoic Acid >98.0%(GC)(T)	B4145	25g	$88
2-Bromo-5-methylbenzoic acid ≥97%(HPLC)	27862	1G	$22.83
2-Bromo-5-methylbenzoic acid ≥97%(HPLC)	27862	5G	$78.82
More product size

Request For Quotation

2-BROMO-5-METHYLBENZOIC ACID Properties

Melting point	136-140 °C
Boiling point	311.6±30.0 °C(Predicted)
Density	1.599±0.06 g/cm3(Predicted)
storage temp.	Sealed in dry,Room Temperature
solubility	Chloroform (Slightly), Methanol (Slightly)
pka	2.92±0.10(Predicted)
form	Solid
color	White to Off-White
InChI	InChI=1S/C8H7BrO2/c1-5-2-3-7(9)6(4-5)8(10)11/h2-4H,1H3,(H,10,11)
InChIKey	ZXMISUUIYPFORW-UHFFFAOYSA-N
SMILES	C(O)(=O)C1=CC(C)=CC=C1Br
CAS DataBase Reference	6967-82-4(CAS DataBase Reference)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H302-H335

Precautionary statements

P264-P270-P280-P301+P312+P330-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P501-P261-P280a-P304+P340-P305+P351+P338-P405-P501a

Hazard Codes

Xi,Xn

Risk Statements

36/37/38-22

Safety Statements

26-36/37/39-37

RIDADR

UN 2811 6.1 / PGIII

WGK Germany

HazardClass

IRRITANT

HS Code

29163990

Storage Class

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects

Hazard Classifications

Acute Tox. 4 Oral

NFPA 704

	0
2		0

2-BROMO-5-METHYLBENZOIC ACID price More Price(63)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	716413	2-Bromo-5-methylbenzoic acid 97%	6967-82-4	1g	$55.9	2026-04-30	Buy
TCI Chemical	B4145	2-Bromo-5-methylbenzoic Acid >98.0%(GC)(T)	6967-82-4	5g	$22	2026-04-30	Buy
TCI Chemical	B4145	2-Bromo-5-methylbenzoic Acid >98.0%(GC)(T)	6967-82-4	25g	$88	2026-04-30	Buy
Chem-Impex	27862	2-Bromo-5-methylbenzoic acid ≥97%(HPLC)	6967-82-4	1G	$22.83	2026-05-19	Buy
Chem-Impex	27862	2-Bromo-5-methylbenzoic acid ≥97%(HPLC)	6967-82-4	5G	$78.82	2026-05-19	Buy

Product number	Packaging	Price	Buy
716413	1g	$55.9	Buy
B4145	5g	$22	Buy
B4145	25g	$88	Buy
27862	1G	$22.83	Buy
27862	5G	$78.82	Buy

2-BROMO-5-METHYLBENZOIC ACID Chemical Properties,Uses,Production

Chemical Properties

Off-white powder

Synthesis

2941-78-8

6967-82-4

The general procedure for the synthesis of 2-bromo-5-methylbenzoic acid from 2-amino-5-methylbenzoic acid was as follows: CuSO4-5H2O (2.82 g, 11.3 mmol), NaBr (2.31 g, 22.4 mmol), and copper scrapings (1.50 g, 23.6 mmol) were boiled in 15 mL of 47% hydrobromic acid until the solution became colorless. Under heating conditions, 5-methyl-phthalamic acid (5.00 g, 33.1 mmol) was dissolved in a solvent mixture of 11.3 mL of 47% aqueous hydrobromic acid and 28 mL of water. The solution was slowly added to the above CuBr solution at 100°C. The temperature of the reaction mixture was maintained at 90-95°C and 25 mL of aqueous solution of NaNO2 (4.53 g, 65.7 mmol) was slowly added with stirring. Upon completion of the reaction, the precipitated acid was collected by diafiltration, washed with 10% aqueous hydrobromic acid and reprecipitated by adding concentrated hydrochloric acid to the alkaline solution. The crude product was treated by activated charcoal and recrystallized from water three times to give 4.00 g (18.6 mmol, 56% yield) of white crystals with melting point of 137-139°C (literature value: 137.6-139°C). The product was analyzed by IR, 1H NMR, 13C NMR and mass spectrometry to confirm the structure, and the results of elemental analyses were consistent with the theoretical values.

References

[1] Phosphorus, Sulfur and Silicon and the Related Elements, 2015, vol. 190, # 12, p. 2142 - 2153
[2] Journal of Organic Chemistry, 1960, vol. 25, p. 1016 - 1020

2-BROMO-5-METHYLBENZOIC ACID Preparation Products And Raw materials

Raw materials

2-Amino-5-methylbenzoic acid Copper Sodium bromide Sodium nitrite Copper(II) sulfate pentahydrate

Hydrogen bromide Diethyl ether Cuprous bromide Hydrochloric acid Sodium hydroxide

1of2

Preparation Products

2-IODO-5-METHYLBENZOIC ACID 5-methyl-2-(2H-1,2,3-triazol-2-yl)benzoic acid METHYL 2-BROMO-5-METHYLBENZOATE

2-BROMO-5-METHYLBENZOIC ACID Suppliers

Global( 236)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Capot Chemical Co.,Ltd.	+8613336195806	sales@capot.com	China	29640	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29815	58
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4241	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
Wuhan Chemwish Technology Co., Ltd	027-67849912	sales@chemwish.com	CHINA	10821	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49979	58
Fuxin Pharmaceutical	+86-021-021-50872116 +8613122107989	contact@fuxinpharm.com	China	10000	58
SIMAGCHEM CORP	+86-5922680277 +86-13806087780	sale@simagchem.com	China	17346	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418671 +8618949823763	sales@tnjchem.com	China	34563	58
Win-Win chemical CO., Limited	+86-0086-577-64498589 +86-15355981851	sales@win-winchemical.com	China	14304	58

Supplier	Advantage
Capot Chemical Co.,Ltd.	60
career henan chemical co	58
Changzhou Ansciep Chemical Co., Ltd.	58
Alchem Pharmtech,Inc.	58
Wuhan Chemwish Technology Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
Fuxin Pharmaceutical	58
SIMAGCHEM CORP	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Win-Win chemical CO., Limited	58

View Lastest Price from 2-BROMO-5-METHYLBENZOIC ACID manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2019-08-06	2-BROMO-5-METHYLBENZOIC ACID 6967-82-4	$1.00	1KG	98%	150KG	Career Henan Chemical Co

2-BROMO-5-METHYLBENZOIC ACID
6967-82-4
$1.00
98%
Career Henan Chemical Co

2-BROMO-5-METHYLBENZOIC ACID Spectrum

2-BROMO-5-METHYLBENZOIC ACID(6967-82-4)FT-IR

6967-82-4(2-BROMO-5-METHYLBENZOIC ACID)Related Search:

2-BROMO-5-METHYLBENZOIC ACID 2-BROMO-4-METHYLBENZOIC ACID 4-BROMO-3-METHYLBENZOIC ACID 2-BROMO-6-METHYLBENZOIC ACID METHYL ESTER Methyl 2-bromo-5-cyanobenzoate

2-Bromo-4-methoxy-5-benzyloxybenzoic acid Broxitalamic acid 4-Bromoisophthalic acid METHYL 2-BROMO-5-METHYLBENZOATE 6-AMINO-2-BROMO-3-METHYLBENZOIC ACID,2-AMINO-6-BROMO-5-METHYLBENZOIC ACID

2-BROMO-6-METHYLBENZOIC ACID 3-Bromo-4-methylbenzoic acid 5-Bromo-2-methylbenzoic acid 4-Bromo-2-methylbenzoic acid 3-Bromo-2-methylbenzoic acid

2-AMINO-3-BROMO-5-METHYLBENZOIC ACID Methyl 4-bromo-3-methylbenzoate Methyl 3-bromo-4-methylbenzoate

1of4

4-Bromo-3-carboxytoluene, 6-Bromo-m-toluic acid 2-BroMo-5-Methylbenzoic Acid, 97+% 2-Bromo-5-methylbenzoicacid,98% 2-BROMO-5-METHYLBENZOIC ACID NSC20686 Benzoic acid,2-bromo-5-methyl- 2-Bromo-5-methylbenzoic Acid > 2-Bromo-5-methylbenzoicaci 6-Bromo-m-toluic Acid Fluralaner-031 Fluralaner Impurity 52 6967-82-4 Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts Benzoic acid Acids & Esters Bromine Compounds