ChemicalBook >> CAS DataBase List >>ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE

ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE

ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE structure

CAS No.: 31037-02-2

Chemical Name:: ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE

Synonyms: ETHYL 5-AMINO-1-METHYL-1H-PYRAZOLE-4-CARBOXYLATE;5-AMINO-1-METHYL-1H-PYRAZOLE-4-CARBOXYLIC ACID ETHYL ESTER;yrazole;AKOS B022231;Pyrazole aMine;ETHYL 5-AMINO-1;BUTTPARK 23\09-41;TIMTEC-BB SBB005505;ART-CHEM-BB B022231;ETHYL 5-AMINO-1-METHYL-1H-PYRAZOLE-4-CA&

CBNumber:: CB6456469

Molecular Formula:: C7H11N3O2

Molecular Weight:: 169.18

MDL Number:: MFCD00051652

MOL File:: 31037-02-2.mol

MSDS File:: SDS

Last updated:2025-07-24 18:13:47

Product description	Number	Pack Size	Price
Ethyl 5-amino-1-methyl-1H-pyrazole-4-carboxylate 97%	687197	5g	$53.4
Ethyl 5-Amino-1-methylpyrazole-4-carboxylate >98.0%(GC)(T)	E0986	5g	$24
Ethyl 5-Amino-1-methylpyrazole-4-carboxylate >98.0%(GC)(T)	E0986	25g	$72
Ethyl 5-amino-1-methylpyrazole-4-carboxylate	449368	100mg	$305
Ethyl 5-Amino-1-	449355	100mg	$305
More product size

Request For Quotation

ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE Properties

Melting point	96-100 °C
Boiling point	121 °C(Press: 0.05 Torr)
Density	1.29±0.1 g/cm3(Predicted)
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
solubility	soluble in Methanol
pka	2.03±0.10(Predicted)
form	Crystals or Crystalline Powder
color	Yellow
Sensitive	Hygroscopic
λmax	257nm(EtOH)(lit.)
BRN	131200
InChI	InChI=1S/C7H11N3O2/c1-3-12-7(11)5-4-9-10(2)6(5)8/h4H,3,8H2,1-2H3
InChIKey	MEUSJJFWVKBUFP-UHFFFAOYSA-N
SMILES	N1(C)C(N)=C(C(OCC)=O)C=N1
CAS DataBase Reference	31037-02-2(CAS DataBase Reference)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

Hazard Codes

Xn,Xi

Risk Statements

36/37/38-22

Safety Statements

36/37/39-26-22-36/37

WGK Germany

HazardClass

IRRITANT

HS Code

29331990

NFPA 704

	1
2		0

ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE price More Price(41)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	687197	Ethyl 5-amino-1-methyl-1H-pyrazole-4-carboxylate 97%	31037-02-2	5g	$53.4	2023-06-20	Buy
TCI Chemical	E0986	Ethyl 5-Amino-1-methylpyrazole-4-carboxylate >98.0%(GC)(T)	31037-02-2	5g	$24	2025-07-31	Buy
TCI Chemical	E0986	Ethyl 5-Amino-1-methylpyrazole-4-carboxylate >98.0%(GC)(T)	31037-02-2	25g	$72	2025-07-31	Buy
Usbiological	449368	Ethyl 5-amino-1-methylpyrazole-4-carboxylate	31037-02-2	100mg	$305	2021-12-16	Buy
Usbiological	449355	Ethyl 5-Amino-1-	31037-02-2	100mg	$305	2021-12-16	Buy

Product number	Packaging	Price	Buy
687197	5g	$53.4	Buy
E0986	5g	$24	Buy
E0986	25g	$72	Buy
449368	100mg	$305	Buy
449355	100mg	$305	Buy

ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE Chemical Properties,Uses,Production

Chemical Properties

yellow crystals or crystalline powder

Uses

ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE features an amino group and a carboxylic acid moiety, which contribute to its reactivity and potential applications in various chemical reactions. The ethyl ester functional group enhances its solubility in organic solvents, making it useful in synthetic chemistry.

Synthesis

94-05-3

60-34-4

ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE

31037-02-2

Example A Synthesis of ethyl 5-amino-1-methyl-1H-pyrazole-4-carboxylate: methylhydrazine (8.6 mL, 162 mmol) was slowly added to a solution of ethyl (ethoxymethylene)cyanoacetate (24.9 g, 147 mmol) in ethanol (250 mL). The reaction mixture was heated to reflux and stirred continuously for 3 days. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure. The resulting residue was purified by recrystallization from a mixed ethyl acetate/petroleum ether solvent to afford a white solid product identified as ethyl 5-amino-1-methyl-1H-pyrazole-4-carboxylate (21.1 g, 85% yield).

References

[1] Journal of Medicinal Chemistry, 2018, vol. 61, # 19, p. 8670 - 8692
[2] Bioorganic and Medicinal Chemistry Letters, 2004, vol. 14, # 17, p. 4585 - 4589
[3] Journal of Heterocyclic Chemistry, 2007, vol. 44, # 4, p. 749 - 755
[4] Patent: EP1512687, 2005, A1. Location in patent: Page/Page column 6
[5] Patent: US5498630, 1996, A

ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE Preparation Products And Raw materials

Raw materials

(E)-Ethyl 2-cyano-3-ethoxyacrylate PYRAZOLE-4-CARBOXYLIC ACID, 3-AMINO-1-METHYL-, ETHYL ESTER Diazene, methyl-, (1E)- (9CI) Ethyl (ethoxymethylene)cyanoacetate Methylhydrazine

Preparation Products

5-AMINO-3-METHYL-1H-PYRAZOLE-4-CARBOXYLIC ACID ETHYL ESTER 1-METHYL-4-ETHOXYCARBONYL PYRAZOLE-5-SULFONYL CHLORIDE Azimsulfuron 1-Methyl-4-Ethoxycarbonyl Pyrazole-5-Sulfonamide (5-bromo-1-methyl-1H-pyrazol-4-yl)methanol

ETHYL 1-METHYL-5-(1H-PYRROL-1-YL)-1H-PYRAZOLE-4-CARBOXYLATE

1of2

ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE Suppliers

Global( 336)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
China Synchem Technology Co.,Ltd.	+86-0552-4929304 +86-18055277008	wangxuhui1985@126.com	China	65	55
Shaanxi Dideu Medichem Co. Ltd	+86-029-81138252 +86-173 9270 1263	1057@dideu.com	China	3999	58
Hebei Chuanghai Biotechnology Co,.LTD	+86-13131129325	sales1@chuanghaibio.com	China	5242	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29735	60
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3009	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29833	58
Changzhou Ditong Chemical Co.,Ltd	+86-0519-88298848	info@edengenechem.com	China	2176	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
Wuhan Chemwish Technology Co., Ltd	027-67849912	sales@chemwish.com	CHINA	10821	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49977	58

Supplier	Advantage
China Synchem Technology Co.,Ltd.	55
Shaanxi Dideu Medichem Co. Ltd	58
Hebei Chuanghai Biotechnology Co,.LTD	58
Capot Chemical Co.,Ltd.	60
Nanjing ChemLin Chemical Industry Co., Ltd.	60
career henan chemical co	58
Changzhou Ditong Chemical Co.,Ltd	58
Alchem Pharmtech,Inc.	58
Wuhan Chemwish Technology Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58

View Lastest Price from ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-05-26	ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE 31037-02-2	US $9.00 / KG	1KG	99.9	1 ton	Hebei Chuanghai Biotechnology Co,.LTD
2025-04-04	ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE 31037-02-2	US $0.00-0.00 / KG	1KG	98%	1ton	Henan Aochuang Chemical Co.,Ltd.
2024-07-29	ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE 31037-02-2	US $1.00 / KG	1KG	99%	20T	Shaanxi Dideu Medichem Co. Ltd

ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE
31037-02-2
US $9.00 / KG
99.9
Hebei Chuanghai Biotechnology Co,.LTD

ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE
31037-02-2
US $0.00-0.00 / KG
98%
Henan Aochuang Chemical Co.,Ltd.

ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE
31037-02-2
US $1.00 / KG
99%
Shaanxi Dideu Medichem Co. Ltd

ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE Spectrum

ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE(31037-02-2)¹HNMR

31037-02-2(ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE)Related Search:

5-AMINO-4-CARBETHOXY-1-PHENYLPYRAZOLE 5-AMINO-1H-PYRAZOLE-4-CARBOXYLIC ACID ETHYL ESTER 5-AMINO-1-(4-NITRO-PHENYL)-1H-PYRAZOLE-4-CARBOXYLIC ACID ETHYL ESTER ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE 1-METHYL-1H-PYRAZOLE-4-CARBOXYLIC ACID

Ethyl pyrazole-4-carboxylate 1H-Pyrazole-4-carboxylicacid,5-amino-1-methyl-(9CI) 1-Methylpyrazole Pyrazole ETHYL 5-OXO-4,5-DIHYDROPYRAZOLO[1,5-A]QUINAZOLINE-3-CARBOXYLATE

ETHYL 1-METHYL-5-(1H-PYRROL-1-YL)-1H-PYRAZOLE-4-CARBOXYLATE ethyl 5,7-dimethylpyrazolo[1,5-a]pyrimidine-3-carboxylate PYRAZOLE-4-CARBOXYLIC ACID, 3-AMINO-1-METHYL-, ETHYL ESTER ETHYL 5-AMINO-1-(4-FLUOROPHENYL)PYRAZOLE-4-CARBOXYLATE ETHYL 5-CHLOROPYRAZOLO[1,5-A]QUINAZOLINE-3-CARBOXYLATE

ETHYL 5-AMINO-1-(4-CHLOROPHENYL)-3-(2-HYDROXYETHOXY)-1H-PYRAZOLE-4-CARBOXYLATE BUTTPARK 138\40-73 ethyl 3-hydrazino-5-methyl-1H-pyrazole-4-carboxylate

1of4

5-AMINO-1-METHYL-1H-PYRAZOLE-4-CARBOXYLIC ACID ETHYL ESTER 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLIC ACID ETHYL ESTER AKOS B022231 TIMTEC-BB SBB005505 ETHYL 3-AMINO-2-METHYLPYRAZOLE-4-CARBOXYLATE ETHYL 5-AMINO-1-METHYL-1H-PYRAZOLE-4-CA& 5-Amino-1-methyl-1H-pyrazole-4-carboxylicacideth ethyl-5-amino-1-methyl-1Hpyrazole carboxylate 3-Amino-2-methyl-2H-pyrazole-4-carboxylic acid ethyl ester Ethyl 5-amino-1-methylpyrazole-4-carboxylate,98% yrazole Pyrazole aMine 5-Amino-4-(ethoxycarbonyl)-1-methyl-1H-pyrazole Ethyl 5-aMino-1-Methylpyrazole-4-carboxylate, 98% 1GR Ethyl5-amino-1-methyl-1H-pyrazole-4-carboxylate,98% -Amino-1-methylpyrazole-4-carboxylic acid ethyl ester Ethyl 1-methyl-5-aminopyrazole-4-carboxylate H-Pyrazole-4-carboxylic acid, 5-amino-1-methyl-, ethyl ester thyl 3-amino-1-methylpyrazole-4-carboxylate thyl 5-amino-1-methyl-4-pyrazolecarboxylate yrazole-4-carboxylic acid, 5-amino-1-methyl-, ethyl ester BUTTPARK 23\09-41 ART-CHEM-BB B022231 ETHYL 5-AMINO-1-METHYL-1H-PYRAZOLE-4-CARBOXYLATE ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLATE 5-AMino-1-Methyl-1H-pyrazole-4-carboxylic acid ethyl ester5-AMino-1-Methyl-1H-pyrazole-4-carboxylic acid ethyl ester ethy1-5-amio-1-methy1-1H-pyrazole-4-carboxylate Ethyl 5-amino-1-methyl-1H-pyrazole-4-carboxylate 1H-Pyrazole-4-carboxylic acid, 5-amino-1-methyl-, ethyl ester ETHYL 5-AMINO-1-METHYLPYRAZOLE-4-CARBOXYLAT Ethyl 5-amino-1-methyl-1H-pyrazole-4-carbo ETHYL 5-AMINO-1 Ethyl5-Amino-1-methylpyrazole-4-carboxylate> DETHYL 5-AMINO-1- METHYLPYRAZOLE-4- CARBOXYLATE 1H-Pyrazole-4-carboxylic acid, 5-amino-1-methyl-, ethyl ester (9CI, ACI) 5-amino-1-methyl-1H-Pyrazole-4-carboxylic acid ethyl ester (9CI ACI) Ethyl 5-amino-1-methyl-1H-pyrazol-4-carboxylate 31037-02-2 313037-02-2 Pharmaceutical Intermediates Pyrazole series Esters Pyrazoles & Triazoles Heterocyclic Compounds Pyrazoles & Triazoles Building Blocks Heterocyclic Building Blocks Pyrazoles bc0001