3-(Methoxymethyl)benzoic acid
- CAS No.
- 32194-76-6
- Chemical Name:
- 3-(Methoxymethyl)benzoic acid
- Synonyms
- Benzoic acid, 3-(MethoxyMethyl)-;3-(methoxymethyl)benzoic acid(SALTDATA: FREE)
- CBNumber:
- CB71490557
- Molecular Formula:
- C9H10O3
- Molecular Weight:
- 166.17
- MDL Number:
- MFCD01871355
- MOL File:
- 32194-76-6.mol
- MSDS File:
- SDS
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302 |
| Precautionary statements | P280-P305+P351+P338 |
| HazardClass | IRRITANT |
| HS Code | 2918999090 |
3-(Methoxymethyl)benzoic acid price More Price(43)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Biosynth | HBA19476 | 3-(Methoxymethyl)benzoic acid | 32194-76-6 | 2.5g | $383.5 | 2026-06-04 | Buy |
| Apolloscientific | OR965593 | 3-(Methoxymethyl)benzoic acid 95% | 32194-76-6 | 100mg | $25 | 2026-06-04 | Buy |
| Apolloscientific | OR965593 | 3-(Methoxymethyl)benzoic acid 95% | 32194-76-6 | 250mg | $30 | 2026-06-04 | Buy |
| Apolloscientific | OR965593 | 3-(Methoxymethyl)benzoic acid 95% | 32194-76-6 | 1g | $88 | 2026-06-04 | Buy |
| Activate Scientific | AS86736 | 3-(Methoxymethyl)benzoic acid 97% | 32194-76-6 | 1g | $149 | 2026-06-04 | Buy |
3-(Methoxymethyl)benzoic acid Chemical Properties, Uses, Production
Synthesis
124-41-4
1129-28-8
32194-76-6
a) Synthesis of 3-(methoxymethyl)benzoic acid: Sodium methanol (0.74 g, 13.8 mmol) was added to a solution of methyl 3-bromomethylbenzoate (1129-28-8, 1.05 g, 4.6 mmol) in anhydrous methanol (30 mL) under argon protection and room temperature. The resulting suspension was stirred and reacted at 50 °C for 2 h. Subsequently, 5 M aqueous potassium hydroxide solution was added and stirring was continued for 1.5 h at 50 °C. The reaction mixture was cooled to room temperature and the pH was adjusted to 2-3 with aqueous hydrochloric acid.The aqueous phase was extracted with ethyl acetate, the organic phases were combined and dried over anhydrous sodium sulfate. The solvent was removed by concentration under reduced pressure to give the target product 3-(methoxymethyl)benzoic acid as a colorless oil (749 mg, 96% yield).LCMS analysis: retention time RtB = 2.47 min; [M + H]+ = 167.0.
References
[1] Patent: US2012/101110, 2012, A1. Location in patent: Page/Page column 70
[2] Patent: US2012/165331, 2012, A1. Location in patent: Page/Page column 27-28
[3] Patent: WO2012/101487, 2012, A1. Location in patent: Page/Page column 65; 66
3-(Methoxymethyl)benzoic acid Preparation Products And Raw materials
Raw materials
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Preparation Products
3-(Methoxymethyl)benzoic acid Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Syntechem Co.,Ltd | info@syntechem.com | China | 12973 | 57 | |
| Wuhan ariel chemical Co., LTD. | 18986259541 18986259541 | sales@3stc.com | China | 3827 | 58 |
| Hangzhou Sage Chemical Co., Ltd. | +86057186818502 13588463833 | info@sagechem.com | China | 10265 | 58 |
| Amatek Scientific Co. Ltd. | 0512-56316828 4008675858 | sales@amateksci.com | China | 9848 | 55 |
| Finetech Industry Limited | 027-87465837 19945049750 | sales@finetechnology-ind.com | China | 9331 | 58 |
| Shanghai YuLue Chemical Co., Ltd. | 021-60345187 13671753212 | lzz841106@aliyun.com | China | 10244 | 55 |
| Shanghai YuanYe Biotechnology Co., Ltd. | 15026964105 | 2881489226@qq.com | China | 89667 | 60 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131885 | 58 |
| Aikon International Limited | 025-66113011 19370895928 | qzhang@aikonchem.com | China | 15390 | 58 |
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