ChemicalBook > Product Catalog >Organic Chemistry >Phosphines >Bis(3 5 3' 5'-dimethoxydibenzylideneace&

Bis(3 5 3' 5'-dimethoxydibenzylideneace&

Request For Quotation
Bis(3 5 3' 5'-dimethoxydibenzylideneace& Suppliers list
Company Name: J & K SCIENTIFIC LTD.  
Tel: 18210857532 18210857532
Email: jkinfo@jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Tel: 4006356688 18621169109
Email: market03@meryer.com
Company Name: Alfa Aesar  
Tel: 400-6106006
Email: saleschina@alfa-asia.com
Company Name: ShangHai DEMO Chemical Co.,Ltd  
Tel: 400-021-7337 2355568890
Email: sales@demochem.com
Company Name: Beijing HwrkChemical Technology Co., Ltd  
Tel: 89508211 18501085097
Email: sales.bj@hwrkchemical.com

Bis(3 5 3' 5'-dimethoxydibenzylideneace& manufacturers
Bis(3 5 3' 5'-dimethoxydibenzylideneace& Basic information
Product Name:Bis(3 5 3' 5'-dimethoxydibenzylideneace&
Synonyms:Bis(3,5,3’,5’-dimethoxydibenzylideneacetone)palladium(0) (Pd(dmdba)2);Bis(3,5,3',5'-dimethoxydibenzylideneacetone)palladium;diMethoxydibenzylideneacetone)palladiuM(0);Bis(3,5,3',5′-diMethoxydibenz;Bis(3,5,3',5'-diMethoxydibenzylideneacetone)palladiuM(0), Pd 13%;PalladiuM,bis[(1E,4E)-(1,2,4,5-h)-1,5-bis(3,5-diMethoxyphenyl)-1,4-pentadien-3-one]-;Bis[(1E,4E)-1,5-bis(3,5-diMethoxyphenyl)…;Bis(3,5,3',5'-dimethoxydibenzylideneacetone)
CAS:811862-77-8
MF:2C21H22O5.Pd
MW:815.22
EINECS:
Product Categories:
Mol File:811862-77-8.mol
Bis(3 5 3' 5'-dimethoxydibenzylideneace& Structure
Bis(3 5 3' 5'-dimethoxydibenzylideneace& Chemical Properties
Melting point 170-178 °C(lit.)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color Red-brown
Water Solubility Insoluble in water.
InChIInChI=1S/2C21H22O5.Pd/c2*1-23-18-9-15(10-19(13-18)24-2)5-7-17(22)8-6-16-11-20(25-3)14-21(12-16)26-4;/h2*5-14H,1-4H3;/b2*7-5+,8-6+;
InChIKeyRTGAJOPJZJDWAX-XVGSOSPHSA-N
SMILES[CH](C1=CC(OC)=CC(OC)=C1)[CH]C(=O)[CH][CH]C1=CC(OC)=CC(OC)=C1.[CH](C1=CC(OC)=CC(OC)=C1)[CH]C(=O)[CH][CH]C1=CC(OC)=CC(OC)=C1.[Pd] |^1:0,11,14,15,26,37,40,41|
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
Bis(3 5 3' 5'-dimethoxydibenzylideneace& Usage And Synthesis
Usessuzuki reaction
UsesBis(3,5,3',5'-dimethoxydibenzylideneacetone)palladium(0) used as catalyst in pharmaceutical research.
General DescriptionBis(3,5,3′,5′-dimethoxydibenzylideneacetone)palladium(0) is a non-phosphine based Pd(0) catalyst that can catalyze the Suzuki–Miyaura reaction of aryl chlorides with arylboronic acids with higher percentage conversion when compared to tris(dibenzylideneacetone)dipalladium(0) [Pd2(dba)3].
reaction suitabilitycore: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
Bis(3 5 3' 5'-dimethoxydibenzylideneace& Preparation Products And Raw materials
Tag:Bis(3 5 3' 5'-dimethoxydibenzylideneace&(811862-77-8) Related Product Information
(XYL)2P(O)H XPhos Pd G3 BrettPhos Pd G3 XPhos Pd G2 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride SPhos Pd G2 RuPhos Pd G2 Tris(dibenzylideneacetone)dipalladium Tris(dibenzylideneacetone)dipalladium Bis(triphenylphosphinepalladium) acetate Bis(dibenzylideneacetone)palladium Bis(tricyclohexylphosphine)palladium(II) Dichloride Tris(dibenzylideneacetone)dipalladium-chloroform adduct Tris(dibenzylideneacetone)dipalladium trans-Dichlorobis(triethylphosphine)palladium(II) Allylchloro[1,3-bis(2,6-di-I-propylphenyl)imidazol-2-ylidene]palladium (II) Dichloro(N,N,N',N'-tetramethylethylenediamine)palladium(II) (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II)