- 2-Acetonaphthone
-
- $10.00 / 25KG
-
2026-03-06
- CAS:93-08-3
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: 100 TON
- 2-Acetonaphthone
-
- $0.00 / 1KG
-
2026-03-06
- CAS:93-08-3
- Min. Order: 1KG
- Purity: 98%min
- Supply Ability: 30tons/month
- 2-Acetonaphthone
-
- $0.00 / 1removed
-
2026-02-26
- CAS:93-08-3
- Min. Order:
- Purity: 99.98%
- Supply Ability: 10g
|
| | 2-Acetonaphthone Basic information |
| | 2-Acetonaphthone Chemical Properties |
| Melting point | 52-56 °C (lit.) | | Boiling point | 300-301 °C (lit.) | | density | 1.12 g/mL at 25 °C(lit.) | | vapor pressure | 0.12Pa at 25℃ | | refractive index | n20/D 1.628(lit.) | | FEMA | 2723 | METHYL BETA-NAPHTHYL KETONE | | Fp | >230 °F | | storage temp. | Sealed in dry,Room Temperature | | solubility | 0.272g/l | | pka | 0[at 20 ℃] | | form | Fine Crystalline Powder and Chunks | | color | White | | Odor | orange-blossom odor | | Odor Type | floral | | biological source | synthetic | | Water Solubility | insoluble | | JECFA Number | 811 | | BRN | 774965 | | Cosmetics Ingredients Functions | PERFUMING
FRAGRANCE | | InChI | 1S/C12H10O/c1-9(13)11-7-6-10-4-2-3-5-12(10)8-11/h2-8H,1H3 | | InChIKey | XSAYZAUNJMRRIR-UHFFFAOYSA-N | | SMILES | CC(=O)c1ccc2ccccc2c1 | | LogP | 2.678 at 25℃ | | CAS DataBase Reference | 93-08-3(CAS DataBase Reference) | | NIST Chemistry Reference | 2-Naphthyl methyl ketone(93-08-3) | | EPA Substance Registry System | 2'-Acetonaphthone (93-08-3) |
| Hazard Codes | Xn,Xi,N | | Risk Statements | 36/37/38-51/53-22-20/21/22 | | Safety Statements | 26-36-61-24/25-22-36/37 | | RIDADR | UN3077 | | WGK Germany | 3 | | RTECS | DB7084000 | | Hazard Note | Irritant | | TSCA | TSCA listed | | HazardClass | 9 | | PackingGroup | III | | HS Code | 29143900 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Aquatic Chronic 2 | | Toxicity | skn-hmn 100% FCTXAV 13,867,75 |
| | 2-Acetonaphthone Usage And Synthesis |
| Physical properties | Methyl β-napthyl ketone has a floral, neroli odor suggestive of orange blossom and a strawberry-like flavor. | | Chemical Properties | 2-Acetonaphthone smells similar to
orange blossomand is a colorless crystalline solid (mp 56 °C). It is usually prepared
by Friedel–Crafts acetylation of naphthalene (with acetyl chloride, acetic anhydride,
etc.) in the presence of aluminumchloride. In polar solvents (e.g., nitrobenzene),
the percentage of the simultaneously formed -isomer is lower. Methyl
2-naphthyl ketone is used in eau de cologne, soap perfumes, and detergents. It
is a good fixative. | | Uses | 2-Acetonaphthone was used in direct time-resolved studies on singlet molecular oxygen phosphorescence in heterogeneous silica gel/cyclohexane systems. | | Uses | 2-Acetonaphthone is a flavoring agent that is a crystalline solid (white or nearly white) with orange blossom-like odor. It is soluble in most fixed oils, slightly soluble in mineral oil and propylene glycol, and insoluble in glycerin. It is obtained by chemical synthesis. | | Definition | ChEBI: 2-acetylnaphthalene is a naphthyl ketone that is naphthalene substituted at position 2 by an acetyl group. | | Preparation | 2-Acetonaphthone may be prepared by Friedel-Crafts reaction of naphthalene, acetyl chloride and AlCl3. | | Synthesis Reference(s) | Journal of the American Chemical Society, 99, p. 3101, 1977 DOI: 10.1021/ja00451a041
The Journal of Organic Chemistry, 55, p. 319, 1990 DOI: 10.1021/jo00288a054
Tetrahedron Letters, 19, p. 147, 1978 DOI: 10.1016/S0040-4039(01)85068-1 | | General Description | 2-Acetonaphthone undergoes efficient photoreduction in the presence of tri-n-butylstannane as hydrogen donor. It is solubilized in air-saturated sodium dodecyl sulphate micelles in D2O or H2O by pulsed nitrogen laser photolysis for triplet sensitized production of singlet oxygen. | | Flammability and Explosibility | Not classified | | Biochem/physiol Actions | Odor at 1.0% | | Safety Profile | Moderately toxic by ingestion. A human skin irritant. Flammable liquid. When heated to decomposition it emits acrid smoke and fumes | | Purification Methods | Separate it from the 1-isomer by fractional crystallisation of the picrate in EtOH (see entry for the 1-isomer above) to m 82o. Decomposition of the picrate with dilute NaOH and extraction with Et2O, then evaporation, give purer 2-acetylnaphthalene. If this residue solidifies, it can be recrystallised from pet ether, EtOH or acetic acid; otherwise it should be distilled in a vacuum and the solid distillate is recrystallised [Gorman & Rodgers J Am Chem Soc 108 5074 1986, Levanon et al. J Phys Chem 91 14 1987]. Purity should be checked by high field NMR spectroscopy. Its oxime has m 145o(dec), and the semicarbazone has m 235o. [Stobbe & Lenzer Justus Liebigs Ann Chem 380 95 1911, Raffauf J Am Chem Soc 72 753 1950, Hunsberger J Am Chem Soc 72 5626 1950, Immediata & Day J Org Chem 5 512 1940, Beilstein 7 IV 1294.] |
| | 2-Acetonaphthone Preparation Products And Raw materials |
|