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4-Bromo-1-methoxy-2-methylbenzene

4-Bromo-1-methoxy-2-methylbenzene Structure
4-Bromo-1-methoxy-2-methylbenzene structure
CAS No.
14804-31-0
Chemical Name:
4-Bromo-1-methoxy-2-methylbenzene
Synonyms
4-BROMO-2-METHYLANISOLE;Bromomethoxytoluene;Methyl-4-bromoanisole;2-METHYL-4-BROMOANISOLE;2-Methoxy-5-bromotoluene;5-BROMO-2-METHOXYTOLUENE;4-Allyloxy BroMo Benzene;4-BROMO-2-METHYLANISOLE 98%;5-Bromo-2-methoxytoluene >5-BROMO-2-METHOXYTOLUENE 98+%
CBNumber:
CB5672408
Molecular Formula:
C8H9BrO
Molecular Weight:
201.06
MDL Number:
MFCD01321139
MOL File:
14804-31-0.mol
MSDS File:
SDS
Last updated:2026-05-28 01:22:27
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4-Bromo-1-methoxy-2-methylbenzene Properties

Melting point 66-69 °C(lit.)
Boiling point 124-125°C 25mm
Density 1.378±0.06 g/cm3 (20 ºC 760 Torr)
Flash point 124-125°C/25mm
storage temp. Sealed in dry,Room Temperature
form powder to crystal
color White to Light yellow
BRN 208224
InChI 1S/C8H9BrO/c1-6-5-7(9)3-4-8(6)10-2/h3-5H,1-2H3
InChIKey UDLRGQOHGYWLCS-UHFFFAOYSA-N
SMILES COc1ccc(Br)cc1C
CAS DataBase Reference 14804-31-0(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
PPE Eyeshields, Gloves, type N95 (US)
Hazard Codes  Xi
Safety Statements  24/25
WGK Germany  3
Hazard Note  Irritant
HS Code  29093090
Storage Class 11 - Combustible Solids
NFPA 704
1
0 0

4-Bromo-1-methoxy-2-methylbenzene price More Price(60)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 523054 4-Bromo-2-methylanisole 98% 14804-31-0 25g $116 2026-04-30 Buy
TCI Chemical B1910 5-Bromo-2-methoxytoluene >98.0%(GC) 14804-31-0 5g $54 2026-04-30 Buy
TCI Chemical B1910 5-Bromo-2-methoxytoluene >98.0%(GC) 14804-31-0 25g $210 2026-04-30 Buy
Strem Chemicals 06-0079 5-Bromo-2-methoxytoluene, min. 98% min.98% 14804-31-0 25g $73 2026-04-30 Buy
Strem Chemicals 06-0079 5-Bromo-2-methoxytoluene, min. 98% min.98% 14804-31-0 100g $185 2026-04-30 Buy
Product number Packaging Price Buy
523054 25g $116 Buy
B1910 5g $54 Buy
B1910 25g $210 Buy
06-0079 25g $73 Buy
06-0079 100g $185 Buy

4-Bromo-1-methoxy-2-methylbenzene Chemical Properties,Uses,Production

Chemical Properties

colorless to light yellow liquid

Uses

4-Bromo-2-methylanisole may be used in the synthesis of 4-isopropyl-2-methylphenol and 4-methoxy-3-methylphenol.

General Description

4-Bromo-2-methylanisole can be prepared by the bromination of o-methylanisole (2-methylanisole). It can also be prepared via reaction between 1-butyl-3-methylimidazolium tribromide [(Bmim)Br3] and an activated aromatic compound. It participates as a substrate for the a-arylation of sulphonamide in a study.

Synthesis

2-Methylanisole

578-58-5

4-BROMO-2-METHYLANISOLE

14804-31-0

General procedure for the synthesis of 2-methyl-4-bromoanisole from 2-methylanisole: In a dry 45 mL reaction tube equipped with a magnetic stirrer (note: air was not removed from the reaction tube), 1 mL of [Bmim]NO3, 0.5 mmol of 2-methylanisole and 0.25 mmol of Br2 were added. The reaction tube was then sealed and the reaction was carried out at 80 °C for 24 hours. Upon completion of the reaction, the mixture was cooled to room temperature and the reaction was terminated by the addition of 3 mL of water. The target product 2-methyl-4-bromoanisole was extracted with dichloromethane (3 x 10 mL). The reaction mixture was analyzed by gas chromatography (GC) to determine the GC yield of the product. In another parallel experiment, the product was purified by column chromatography and structurally characterized using 1H NMR and 13C NMR.

References

[1] Helvetica Chimica Acta, 1983, vol. 66, # 4, p. 1068 - 1077
[2] Synthetic Communications, 2007, vol. 37, # 2, p. 323 - 328
[3] Chemistry - A European Journal, 2015, vol. 21, # 34, p. 11976 - 11979
[4] Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1999, vol. 38, # 5, p. 603 - 604

4-Bromo-1-methoxy-2-methylbenzene Preparation Products And Raw materials

Raw materials

2-Methylanisole

Preparation Products

4-METHOXY-3-METHYLPHENYLBORONIC ACID 4-Methoxy-3-methylphenylmagnesium bromide

4-Bromo-1-methoxy-2-methylbenzene Suppliers

Global( 205)Suppliers
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
ChangShu Haitian Fine Chemicals Co.,Ltd 13913622609 974295387@qq.com China 192 61
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shijiazhuang Sdyano Fine Chemical Co., Ltd. 0311-89250318 13582355795 master@sjzsdyn.com China 2776 65
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35884 56
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18187 66
JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078 sales@jingyan-chemical.com China 9963 60
Shanghai Sinch Parmaceuticals Tech. Co. Ltd. +86-21-54098501 sales@sinch.com.cn China 11592 64
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Alfa Aesar 84
TCI (Shanghai) Development Co., Ltd. 81
ChangShu Haitian Fine Chemicals Co.,Ltd 61
Energy Chemical 61
Shijiazhuang Sdyano Fine Chemical Co., Ltd. 65
Wuhan Chemwish Technology Co., Ltd 56
Capot Chemical Co., Ltd 66
JinYan Chemicals(ShangHai) Co.,Ltd. 60
Shanghai Sinch Parmaceuticals Tech. Co. Ltd. 64

View Lastest Price from 4-Bromo-1-methoxy-2-methylbenzene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-BROMO-2-METHYLANISOLE pictures 2019-12-24 4-BROMO-2-METHYLANISOLE
14804-31-0
 $1.00 1g 98%min Career Henan Chemical Co

4-Bromo-1-methoxy-2-methylbenzene Spectrum

4-BROMO-2-METHYLANISOLE(14804-31-0)MS4-BROMO-2-METHYLANISOLE(14804-31-0)1HNMR4-BROMO-2-METHYLANISOLE(14804-31-0)13CNMR4-BROMO-2-METHYLANISOLE(14804-31-0)IR14-BROMO-2-METHYLANISOLE(14804-31-0)IR2

14804-31-0(4-Bromo-1-methoxy-2-methylbenzene)Related Search:

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1of4

5-BROMO-2-METHOXYTOLUENE Bromomethoxytoluene 2-METHYL-4-BROMOANISOLE 5-BROMO-2-METHOXYTOLUENE 98+% 4-BROMO-2-METHYLANISOLE 98% 4-Bromo-2-methylanisole, 98+% Benzene,4-bromo-1-methoxy-2-methyl- 1-(bromomethoxy)-2-methylbenzene 1-Bromo-3-methyl-4-methoxybenzene 1-Methoxy-2-methyl-4-bromobenzene 2-Methoxy-5-bromotoluene Methyl(2-methyl-4-bromophenyl) ether 4-Allyloxy BroMo Benzene 5-Bromo-2-methoxytoluene, 4-Bromo-1-methoxy-2-methylbenzene, 4-Bromo-2-methylphenyl methyl ether Methyl-4-bromoanisole 5-Bromo-2-methoxytoluene > 4-BROMO-2-METHYLANISOLE 14804-31-0 4804-31-0 Building Blocks ARYL HALIDE Organic Building Blocks Ethers Oxygen Compounds Aromatic Hydrocarbons (substituted) & Derivatives Anisoles, Alkyloxy Compounds & Phenylacetates Bromine Compounds