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5-BROMO-2-METHOXYANILINE

5-BROMO-2-METHOXYANILINE structure

CAS No.: 6358-77-6

Chemical Name:: 5-BROMO-2-METHOXYANILINE

Synonyms: 5-bromo-o-anisidine;2-amino-4-bromoanisole;4-Bromo-2-aminoanisole;2-Methoxy-5-bromoaniline;5-BROMO-2-METHOXYANILINE;5-Bromo-2-methoxyaniline >5-Bromo-2-methoxyaniline 98%;5-bromo-2-methoxybenzenamine;5-Bromo-2-methoxyaniline, 97%;Benzenamine, 5-bromo-2-methoxy-

CBNumber:: CB8454146

Molecular Formula:: C7H8BrNO

Molecular Weight:: 202.05

MDL Number:: MFCD04037882

MOL File:: 6358-77-6.mol

MSDS File:: SDS

Last updated:2026-05-28 03:18:57

Product description	Number	Pack Size	Price
5-Bromo-2-methoxyaniline 95%	750808	5g	$86
5-Bromo-2-methoxyaniline >97.0%(T)	B3828	1g	$33
5-Bromo-2-methoxyaniline >97.0%(T)	B3828	5g	$100
5-Bromo-2-methoxyaniline 98%	AS38732	5g	$31
5-Bromo-2-methoxyaniline 98%	AS38732	25g	$78
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5-BROMO-2-METHOXYANILINE Properties

Melting point	94-96°C
Boiling point	275℃
Density	1.531
Flash point	120℃
storage temp.	2-8°C
pka	3.46±0.10(Predicted)
form	powder to crystal
color	Light yellow to Brown
Water Solubility	Slightly soluble in water.
InChI	InChI=1S/C7H8BrNO/c1-10-7-3-2-5(8)4-6(7)9/h2-4H,9H2,1H3
InChIKey	OPGNSNDTPPIYPG-UHFFFAOYSA-N
SMILES	C1(N)=CC(Br)=CC=C1OC
CAS DataBase Reference	6358-77-6(CAS DataBase Reference)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H302-H317

Precautionary statements

P280-P301+P312+P330-P302+P352

Hazard Codes

Xi,Xn

Risk Statements

20/21/22-33-43-22

Safety Statements

26-33-36/37/39-45-36/37

RIDADR

UN2811

WGK Germany

HazardClass

6.1

PackingGroup

III

HS Code

2921490090

Storage Class

11 - Combustible Solids

Hazard Classifications

Acute Tox. 4 Oral
Skin Sens. 1

NFPA 704

	0
2		0

5-BROMO-2-METHOXYANILINE price More Price(53)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	750808	5-Bromo-2-methoxyaniline 95%	6358-77-6	5g	$86	2026-04-30	Buy
TCI Chemical	B3828	5-Bromo-2-methoxyaniline >97.0%(T)	6358-77-6	1g	$33	2026-04-30	Buy
TCI Chemical	B3828	5-Bromo-2-methoxyaniline >97.0%(T)	6358-77-6	5g	$100	2026-04-30	Buy
Activate Scientific	AS38732	5-Bromo-2-methoxyaniline 98%	6358-77-6	5g	$31	2026-06-04	Buy
Activate Scientific	AS38732	5-Bromo-2-methoxyaniline 98%	6358-77-6	25g	$78	2026-06-04	Buy

Product number	Packaging	Price	Buy
750808	5g	$86	Buy
B3828	1g	$33	Buy
B3828	5g	$100	Buy
AS38732	5g	$31	Buy
AS38732	25g	$78	Buy

5-BROMO-2-METHOXYANILINE Chemical Properties,Uses,Production

Chemical Properties

Off-white powder

Uses

5-Bromo-2-methoxyaniline is used as a pharmaceutical intermediate.

Synthesis

33696-00-3

6358-77-6

General procedure for the synthesis of 5-bromo-2-methoxyaniline from 2-nitro-4-bromoanisole: 1. Preparation of Intermediate 11A: An ethanol (65 mL) solution of 4-bromo-1-methoxy-2-nitrobenzene (2.00 g, 8.62 mmol), zinc powder (5.64 g, 86.0 mmol), and ammonium chloride (4.61 g, 86.0 mmol) was stirred for 2 hours at room temperature. 2. Upon completion of the reaction, the reaction mixture was diluted with ethyl acetate (EtOAc) and filtered through diatomaceous earth (CELITE). 3. The filtrate was concentrated by evaporation to give Intermediate 11A (1.74 g, 100% yield) as an off-white solid. 4. Mass spectral analysis (LCMS-ESI) of Intermediate 11A showed m/z 202,204 ([M+H] , [M+2+H]) , and a retention time (RT) of 0.70 min (Method J).

References

[1] Patent: WO2014/22343, 2014, A1. Location in patent: Paragraph 00169
[2] Bioorganic and Medicinal Chemistry, 2013, vol. 21, # 5, p. 1357 - 1366
[3] Journal fuer Praktische Chemie (Leipzig), 1935, vol. <2> 143, p. 18,24
[4] Gazzetta Chimica Italiana, 1932, vol. 62, p. 51,54
[5] Justus Liebigs Annalen der Chemie, 1883, vol. 217, p. 44

5-BROMO-2-METHOXYANILINE synthesis

Synthesis of 5-BROMO-2-METHOXYANILINE from 4-BROMO-2-NITROANISOLE

5-BROMO-2-METHOXYANILINE Preparation Products And Raw materials

Raw materials

4,5-dibromo-2-methoxyaniline 4-Bromo-2-nitrophenol 3-(5-BROMO-2-METHOXYPHENYL)PROPANOIC ACID 2-Acetamido-4-bromoanisole 4-BROMO-2-NITROANISOLE

Water Sulfuric acid Hydrochloric acid Iron Tin tetrachloride

N-(2-Methoxyphenyl)acetamide 4-Bromoanisole

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Preparation Products

2,7-Dibromophenazine 5-BROMO-2-METHOXYBENZENESULFONYL CHLORIDE Azoic Coupling Component 6 4-hydroxy-3-(5-methyl-1H-pyrazol-1- yl)benzaldehyde

5-BROMO-2-METHOXYANILINE Suppliers

Global( 182)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
Nanjing Dolon Biotechnology Co.,Ltd.	18905173768	52513593@qq.com	CHINA	2972	58
Accela ChemBio Inc.	+1-858-6993322	info@accelachem.com	United States	21193	58
Changzhou Ditong Chemical Co.,Ltd	+86-0519-88298848	info@edengenechem.com	China	2165	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
Wuhan Chemwish Technology Co., Ltd	027-67849912	sales@chemwish.com	CHINA	10821	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49979	58
career henan chemical co	+86-0371-86658258 +8613203830695	factory@coreychem.com	China	29792	58
Fuxin Pharmaceutical	+86-021-021-50872116 +8613122107989	contact@fuxinpharm.com	China	10000	58
Antai Fine Chemical Technology Co.,Limited	18503026267	info@antaichem.com	CHINA	9636	58

Supplier	Advantage
ATK CHEMICAL COMPANY LIMITED	60
Nanjing Dolon Biotechnology Co.,Ltd.	58
Accela ChemBio Inc.	58
Changzhou Ditong Chemical Co.,Ltd	58
Alchem Pharmtech,Inc.	58
Wuhan Chemwish Technology Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58
Fuxin Pharmaceutical	58
Antai Fine Chemical Technology Co.,Limited	58

View Lastest Price from 5-BROMO-2-METHOXYANILINE manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2021-07-13	5-BROMO-2-METHOXYANILINE 6358-77-6	$10.00-15.00	1KG	99%+ HPLC		Zhuozhou Wenxi import and Export Co., Ltd
2021-07-10	5-BROMO-2-METHOXYANILINE 6358-77-6	$10.00-15.00	1KG	99%+ HPLC		Zhuozhou Wenxi import and Export Co., Ltd
2019-12-31	5-BROMO-2-METHOXYANILINE 6358-77-6	$1.00	1KG	99%	200kg	Career Henan Chemical Co

5-BROMO-2-METHOXYANILINE
6358-77-6
$10.00-15.00
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

5-BROMO-2-METHOXYANILINE
6358-77-6
$10.00-15.00
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

5-BROMO-2-METHOXYANILINE
6358-77-6
$1.00
99%
Career Henan Chemical Co

5-BROMO-2-METHOXYANILINE Spectrum

5-BROMO-2-METHOXYANILINE(6358-77-6)¹HNMR

6358-77-6(5-BROMO-2-METHOXYANILINE)Related Search:

4-BROMO-2-NITROANISOLE 4-BROMO-2-FLUORO-6-NITROANISOLE 6-BROMO-2H-1,4-BENZOXAZIN-3(4H)-ONE 5-BROMO-2-BENZOXAZOLINONE 97 LACMOID

2-Bromo-5-methoxyaniline, HCl 4-BROMO-2-METHOXYANILINE[2-AMINO-5-BROMOANISOLE] ,4-BROMO-2-METHOXYANILINE 2-BROMO-5-METHOXYANILINE 4-Bromoanisole 4-BROMO-3-METHOXYANILINE

4-Chlorophenethylamine 2-BROMO-4-METHOXY-PHENYLAMINE 5,5'-DIBROMO BAPTA AM NS-2028 LABOTEST-BB LT01143471

2-BROMO-4-METHOXYANILINE Hydrochloride 3-Bromo-4-methoxyaniline hydrochloride 2-BROMO-6-METHOXYANILINE

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5-BROMO-2-METHOXYANILINE 5-bromo-2-methoxybenzenamine 2-amino-4-bromoanisole 5-bromo-o-anisidine 5-Bromo-2-methoxyaniline 98% 2-Amino-4-bromoanisole, 5-Bromo-o-anisidine 2-Methoxy-5-bromoaniline 4-Bromo-2-aminoanisole 5-Bromo-2-methoxyaniline > Benzenamine, 5-bromo-2-methoxy- 5-Bromo-2-methoxyaniline, 97% 6358-77-6 Amines blocks Bromides